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Numerous dependencies between geometrical, energetic and topological parameters of complexes considered were found, since various theoretical approaches were applied: Quantum Theory of \u2018Atoms in Molecules\u2019 (QTAIM), Natural Bond Orbital (NBO) method and energy decomposition analysis (EDA). It was confirmed that complexes of dihydrogen and cyclopropane are linked through the A\u2212H\u2026\u03c3 interactions that may be classified as hydrogen bonds. In the case of complexes of cyclobutane such hydrogen bonds are rather weak. Other type and also weak A\u2212H\u2026C hydrogen bonds are formed for complexes with cyclopentane.<\/jats:p>","DOI":"10.1002\/cphc.201900045","type":"journal-article","created":{"date-parts":[[2019,1,15]],"date-time":"2019-01-15T13:44:56Z","timestamp":1547559896000},"page":"565-574","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["A\u2212H\u2026\u03c3 Hydrogen Bonds: Dihydrogen and Cycloalkanes as Proton Acceptors"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4161-2938","authenticated-orcid":false,"given":"S\u0142awomir J.","family":"Grabowski","sequence":"first","affiliation":[{"name":"Faculty of Chemistry University of the Basque Country and Donostia International Physics Center (DIPC)  P.K. 1072 20080 Donostia Spain"},{"name":"IKERBASQUE, Basque Foundation for Science  48011 Bilbao Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,2]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00156a032"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199525071"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9825332"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889810019680"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/poc.3109"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(01)00998-8"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2004.05.123"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2006.10.069"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp070530i"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja991795g"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.453535"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1569911"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp0306343"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp0310403"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.469240"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp971893t"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0353-z"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.442424"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp20560a"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.7b11952"},{"key":"e_1_2_6_21_1","unstructured":"Gaussian 16 Revision A.03 M.\u2005J. 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