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Relativistic quantum calculations on complexes formed between halide anions and a series of Y<jats:sub>3<\/jats:sub>C\u2212X (Y=F to X, X=I, At) halogen\u2010bond donors disclosed unexpected trends, <jats:italic>e.\u2009g<\/jats:italic>., At<jats:sub>3<\/jats:sub>C\u2212At revealing a weaker donating ability than I<jats:sub>3<\/jats:sub>C\u2212I despite a stronger polarizability. All the observed peculiarities have their origin in a specific component of C\u2212Y bonds: the charge\u2010shift bonding. Descriptors of the Quantum Chemical Topology show that the halogen\u2010bond strength can be quantitatively anticipated from the magnitude of charge\u2010shift bonding operating in Y<jats:sub>3<\/jats:sub>C\u2212X. The charge\u2010shift mechanism weakens the ability of the halogen atom X to engage in halogen bonds. 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