{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T20:40:48Z","timestamp":1760388048935,"version":"build-2065373602"},"reference-count":58,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2020,4,7]],"date-time":"2020-04-07T00:00:00Z","timestamp":1586217600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"name":"Technical University Chemnitz"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2020,5,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Material development requires in many cases information about the necessary stability of the materials against oxidation, which is encoded in the chemical activity of the constituting elements. Determination of the chemical activity is tedious, especially for metallic materials at or close to ambient temperature. To determine the chemical activity of Zn at ambient temperature, electromotive force (EMF) measurements on the intermetallic compounds ZnPd, ZnPt and Cu<jats:sub>5<\/jats:sub>Zn<jats:sub>8<\/jats:sub> within their respective homogeneity range were conducted. The single\u2010phase nature of the samples was confirmed by powder X\u2010ray diffraction, light microscopy as well as SEM\/EDX analysis. To exclude oxidation, and therefore faulty determination of the electrochemical potentials, a method was developed to conduct the electrochemical measurements under non\u2010corrosive conditions in inert atmosphere. Corrosion by the electrolyte was avoided using anhydrous dimethylformamide as aprotic solvent. From the EMF the respective intrinsic activities of zinc in the corresponding intermetallic compounds was determined. Measurements on Cu<jats:sub>5<\/jats:sub>Zn<jats:sub>8<\/jats:sub> and comparison to available data in literature verified the developed method allowing to retrieve thermodynamic data of ZnPd and ZnPt for the first time at ambient temperature. The herein developed and easy\u2010to\u2010use methodology is applicable to a wide range of metallic material by choosing appropriate compositions of the electrolyte and has the potential to boost material development.<\/jats:p>","DOI":"10.1002\/cphc.201901218","type":"journal-article","created":{"date-parts":[[2020,3,24]],"date-time":"2020-03-24T13:16:38Z","timestamp":1585055798000},"page":"977-986","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Corrosion\u2010Free EMF Measurements of Zinc\u2010Based Intermetallic Compounds at Ambient Temperature"],"prefix":"10.1002","volume":"21","author":[{"given":"Ren\u00e9","family":"Kriegel","sequence":"first","affiliation":[{"name":"Faculty of Natural Sciences, Institute of Chemistry Materials for Innovative Energy Concepts Technische Universit\u00e4t Chemnitz  Stra\u00dfe der Nationen 62 09107 Chemnitz Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2914-0600","authenticated-orcid":false,"given":"Marc","family":"Armbr\u00fcster","sequence":"additional","affiliation":[{"name":"Faculty of Natural Sciences, Institute of Chemistry Materials for Innovative Energy Concepts Technische Universit\u00e4t Chemnitz  Stra\u00dfe der Nationen 62 09107 Chemnitz Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,4,7]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410738"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410738"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/co200007w"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2062"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1088\/1468-6996\/15\/3\/034803"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b05732"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3347"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201503000"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04566"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209587"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209587"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2016.01.006"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp1103164"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b01961"},{"key":"e_1_2_7_13_1","unstructured":"J. Hagen Technische Katalyse Wiley-VCH Weinheim 2008."},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60019a001"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/tf9383400011"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.99.016105"},{"key":"e_1_2_7_17_1","unstructured":"P. Schmidt Habilitation Technische Universit\u00e4t Dresden 2007."},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201101459"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201101459"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11837-007-0007-6"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2428639"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02698252"},{"key":"e_1_2_7_22_1","unstructured":"O. Kubaschewski E.\u2005L. Evans Metallurgische Thermochemie VEB Verlag Technik Berlin 1959."},{"key":"e_1_2_7_23_1","first-page":"169","volume":"46","author":"Schwitzgebel G.","year":"1974","journal-title":"Chem. Ing. Tech."},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1524\/zpch.1985.146.1.087"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1524\/zpch.1975.95.1-3.015"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(72)90061-2"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2018.01.385"},{"key":"e_1_2_7_28_1","unstructured":"in EC-Lab (Version 11.01) Bio-Logic - Science Instruments City 2016."},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2448"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2006.03.016"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201402086"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1109\/MEI.2015.7126071"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02068"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1361\/105497103770330541"},{"key":"e_1_2_7_35_1","doi-asserted-by":"crossref","first-page":"428","DOI":"10.1515\/zpch-1933-16436","volume":"164","author":"\u00d6lander A.","year":"1933","journal-title":"Z. Phys. Chem."},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/j150581a036"},{"key":"e_1_2_7_37_1","first-page":"1287","volume":"245","author":"Wilder T. C.","year":"1969","journal-title":"Trans. Metall. Soc. AIME."},{"key":"e_1_2_7_38_1","unstructured":"T.\u2005B. Massalski Binary Alloy Phase Diagrams ASM International Ohio 1990."},{"key":"e_1_2_7_39_1","first-page":"1395","volume":"245","author":"Pemsler J. P.","year":"1969","journal-title":"Trans. Metall. Soc. AIME."},{"key":"e_1_2_7_40_1","first-page":"183","volume":"285","author":"Cunat C.","year":"1977","journal-title":"Ser. C."},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02647656"},{"key":"e_1_2_7_42_1","first-page":"143","volume":"171","author":"Birchenall C. E.","year":"1947","journal-title":"Trans. Am. Inst. Min. Metall. Pet. Eng."},{"key":"e_1_2_7_43_1","first-page":"323","volume":"188","author":"Herbenar A. W.","year":"1950","journal-title":"Trans. Am. Inst. Min. Metall. Pet. Eng."},{"key":"e_1_2_7_44_1","first-page":"627","volume":"48","author":"Schneider A.","year":"1942","journal-title":"Z. Elektrochem. Angew. Phys. Chem."},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/TF9585400799"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02643454"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(57)90102-5"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(64)90146-4"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1026096817096"},{"key":"e_1_2_7_50_1","unstructured":"D.\u2005R. Gaskell Introduction to the Thermodynamics of Matreials Taylor & Francis Group New York\/London 2008."},{"key":"e_1_2_7_51_1","first-page":"141","volume":"68","author":"Chiang T. H.","year":"1977","journal-title":"Z. Metallkd."},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(75)90036-X"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2133536"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2010.05.146"},{"key":"e_1_2_7_55_1","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1515\/ijmr-2006-0071","volume":"97","author":"Huang Y. Z.","year":"2006","journal-title":"Int. J. Mater. Res."}],"container-title":["ChemPhysChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcphc.201901218","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.201901218","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cphc.201901218","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.201901218","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T20:00:24Z","timestamp":1760385624000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cphc.201901218"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,4,7]]},"references-count":58,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2020,5,18]]}},"alternative-id":["10.1002\/cphc.201901218"],"URL":"https:\/\/doi.org\/10.1002\/cphc.201901218","archive":["Portico"],"relation":{},"ISSN":["1439-4235","1439-7641"],"issn-type":[{"type":"print","value":"1439-4235"},{"type":"electronic","value":"1439-7641"}],"subject":[],"published":{"date-parts":[[2020,4,7]]},"assertion":[{"value":"2019-12-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-04-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}