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UV irradiation decreases the higher energy ZnNC isomer in favor of the lower energy ZnCN product. Cadmium and mercury atoms produce analogous MCN primary molecules. Laser ablation of metals also produces plume radiation which initiates H\u2010atom detachment from HCN. The freed H atom can add to CN radical to produce the HNC isomer. The argon matrix also traps the higher energy but more intensely absorbing isocyanide molecules. Further reactions with H atoms generate HMCN and HMNC hydrides, which can be observed by virtue of their C\u2212N stretches and intense M\u2212H stretches. Computational modeling of IR spectra and relative energies guides the identification of reaction products by providing generally reliable frequency differences within the Zn, Cd and Hg family of products, and estimating isotopic shifts using to <jats:sup>13<\/jats:sup>C and <jats:sup>15<\/jats:sup>N isotopic substitution for comparison with experimental data.<\/jats:p>","DOI":"10.1002\/cphc.202100011","type":"journal-article","created":{"date-parts":[[2021,8,14]],"date-time":"2021-08-14T01:38:35Z","timestamp":1628905115000},"page":"1914-1934","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Cyanides, Isocyanides, and Hydrides of Zn, Cd and Hg from Metal Atom and HCN Reactions: Matrix Infrared Spectra and Electronic Structure 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