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Triarylamine was introduced to the porphyrin moiety at the <jats:italic>meso<\/jats:italic>\u2010position as an electron donor, enhancing the charge carrier mobility. All the synthesized zinc porphyrins are thermally stable with a decomposition temperature over 178\u2009\u00b0C. High frontier molecular orbitals levels of these compounds make them stable donor materials. SEM analysis of zinc porphyrins fabricated by spin\u2010coating resulted in diversely self\u2010assembled films. Field\u2010effect transistors were fabricated using bottom\u2010gate\/top\u2010contact architecture (BGTC) by solution\u2010processable technique. The higher charge carrier mobility of 5.17\u2005cm<jats:sup>2<\/jats:sup>\/Vs with on\/off of 10<jats:sup>6<\/jats:sup> was obtained for trifluoromethyl substituted compound due to better molecular packing. In addition, GIXRD analysis revealed zinc porphyrins films crystalline nature, which supports its better charge carrier mobility. The present investigation has validated that zinc porphyrin building blocks are an attractive candidate for p\u2010channel OFET devices.<\/jats:p>","DOI":"10.1002\/cphc.202200375","type":"journal-article","created":{"date-parts":[[2022,9,23]],"date-time":"2022-09-23T15:39:48Z","timestamp":1663947588000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["High\u2010Performance Organic Field\u2010effect Transistors from Functionalized Zinc <i>Meso<\/i>\u2010Porphyrins"],"prefix":"10.1002","volume":"24","author":[{"given":"Komal","family":"Kurlekar","sequence":"first","affiliation":[{"name":"Department of Chemistry Central University Of Tamil Nadu  Thiruvarur 610 005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anshika","family":"Anjali","sequence":"additional","affiliation":[{"name":"Department of Chemistry Central University Of Tamil Nadu  Thiruvarur 610 005 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