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The benzyne molecule is found to adsorb preferentially via the strained triple bond on one dimer of the Si(001) surface which results in an intact <jats:italic>\u03c0<\/jats:italic> system covalently bound to the surface. With increasing coverage, the molecules primarily adsorb along the dimer rows; on stepped surfaces, these molecular wires are all oriented in the same direction.<\/jats:p>","DOI":"10.1002\/cphc.202200404","type":"journal-article","created":{"date-parts":[[2022,9,27]],"date-time":"2022-09-27T15:25:33Z","timestamp":1664292333000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Towards <i>\u03c0<\/i>\u2010wires on a semiconductor surface: Benzyne on Si(001)"],"prefix":"10.1002","volume":"23","author":[{"given":"T.","family":"Glaser","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Angewandte Physik and Zentrum f\u00fcr Materialforschung Justus-Liebig-Universit\u00e4t Giessen  Heinrich-Buff-Ring 16 D-35392 Giessen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"Tripp","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie, Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 D-35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J.\u2010N.","family":"Luy","sequence":"additional","affiliation":[{"name":"Wilhelm-Ostwald-Institut f\u00fcr Physikalische und Theoretische Chemie Universit\u00e4t Leipzig  Linn\u00e9stra\u00dfe 2 D-04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6759-8559","authenticated-orcid":false,"given":"R.","family":"Tonner\u2010Zech","sequence":"additional","affiliation":[{"name":"Wilhelm-Ostwald-Institut f\u00fcr Physikalische und Theoretische Chemie Universit\u00e4t Leipzig  Linn\u00e9stra\u00dfe 2 D-04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4776-8549","authenticated-orcid":false,"given":"U.","family":"Koert","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie, Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 D-35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4676-8715","authenticated-orcid":false,"given":"M.","family":"D\u00fcrr","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Angewandte Physik and Zentrum f\u00fcr Materialforschung Justus-Liebig-Universit\u00e4t Giessen  Heinrich-Buff-Ring 16 D-35392 Giessen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,9,27]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390151"},{"volume-title":"Dehydrobenzene and Cycloalkynes","year":"1967","author":"Hoffmann R. 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