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In this research, we prepare some assembled organoruthenium through coordination reaction between Ru(<jats:italic>p<\/jats:italic>\u2010Cymene)Cl<jats:sub>2<\/jats:sub> and bridge\u2010linking ligands. It is a creative approach for Ru(<jats:italic>p<\/jats:italic>\u2010Cymene)Cl<jats:sub>2<\/jats:sub> conversion into heterogeneous particles. The rigidity of bridge\u2010linking ligand enables assembled organoruthenium to have highly ordered crystalline structure, even show clear crystal lattice with spacing of 0.19\u2005nm. XPS shows the N\u2212Ru bond are formed between bridge\u2010linking ligand and Ru(<jats:italic>p<\/jats:italic>\u2010Cymene)Cl<jats:sub>2<\/jats:sub>. The assembled organoruthenium has high abundant active sites for formaldehyde decomposition at low temperature. The reaction rate could increase linearly with temperature and formaldehyde concentration, with a TOF of 2420\u2005h<jats:sup>\u22121<\/jats:sup> at 90\u2009\u00b0C. It is promising for gaseous formaldehyde decomposition in wet air or nitrogen. Formaldehyde conversion is up to 95\u2009% over Ru\u2010DAPM is 4,4\u2032\u2010diaminodiphenylmethane at 90\u2009\u00b0C in air. Gaseous formaldehyde decomposition is a two\u2010steps process under oxygen\u2010free condition. Firstly, formaldehyde dissolve in water, and be converted into hydrogen and formic acid through formaldehyde\u2010water shift reaction. Then intermediate formic acid will further decompose into hydrogen and carbon dioxide. We also find formaldehyde decomposition is a synergetic catalysis process of oxygen and water in moist air. Oxygen is conducive to formic acid desorption and decomposition on the active sites, so assembled organoruthenium exhibit slightly higher conversion for formaldehyde decomposition in moist air. This work proposes a distinctive method for gaseous formaldehyde decomposition in the air, which is entirely different from formaldehyde photocatalysis or thermocatalysis oxidation.<\/jats:p>","DOI":"10.1002\/cphc.202200695","type":"journal-article","created":{"date-parts":[[2022,12,2]],"date-time":"2022-12-02T02:30:40Z","timestamp":1669948240000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Assembled Organoruthenium(II) for Formaldehyde Decomposition and Hydrogen Production"],"prefix":"10.1002","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0731-8842","authenticated-orcid":false,"given":"Yangbin","family":"Shen","sequence":"first","affiliation":[{"name":"Institute of Materials Science and Devices School of Materials Science and Engineering Suzhou University of Science and Technology  Suzhou 215009 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Xu","sequence":"additional","affiliation":[{"name":"Institute of Materials Science and Devices School of Materials Science and Engineering Suzhou University of Science and Technology  Suzhou 215009 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulu","family":"Zhan","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,12,23]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.59"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2014.05.015"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC01256H"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202101240"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201800636"},{"key":"e_1_2_8_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201800636"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2018.12.011"},{"key":"e_1_2_8_8_1","unstructured":"\u00a0"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1058923"},{"key":"e_1_2_8_10_2","volume":"13","author":"Li N.","year":"2022","journal-title":"Nat. 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