{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:37:25Z","timestamp":1786977445776,"version":"build-2736575974"},"reference-count":47,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2023,6,20]],"date-time":"2023-06-20T00:00:00Z","timestamp":1687219200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2023,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Among the conglomeration of hydrogen bond donors, the C\u2212H group is prevalent in chemistry and biology. In the present work, CHCl\n                    <jats:sub>3<\/jats:sub>\n                    has been selected as the hydrogen bond donor and are X(CH\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    are the hydrogen bond acceptors. Formation of C\u2212H\u22c5\u22c5\u22c5X hydrogen bond under the matrix isolation condition is confirmed by the observation of red\u2010shift in the C\u2212H stretching frequency of CHCl\n                    <jats:sub>3<\/jats:sub>\n                    and comparison with the simulated spectra. Stabilisation energy of all the three complexes is almost equal although the observed red\u2010shift for the C\u2212H\u22c5\u22c5\u22c5O complex is less compared to the C\u2212H\u22c5\u22c5\u22c5S\/Se complexes. The nature and origin of the hydrogen bond have been delineated using Natural Bond Orbital, Atoms in Molecules, Non\u2010Covalent Interaction analyses, and Energy Decomposition Analysis. Charge transfer is found to be proportional to the observed red\u2010shift. This work provides the first impression of C\u2212H\u22c5\u22c5\u22c5Se hydrogen bond and its comparison with C\u2212H\u22c5\u22c5\u22c5O\/S hydrogen bond interaction under experimental condition.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202300124","type":"journal-article","created":{"date-parts":[[2023,5,15]],"date-time":"2023-05-15T04:58:51Z","timestamp":1684126731000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["An Experimental Exploration of C\u2212H\n                    <i>\u22c5\u22c5\u22c5<\/i>\n                    X Hydrogen Bond in [CHCl\n                    <sub>3<\/sub>\n                    \u2212X(CH\n                    <sub>3<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    ] Complexes (X=O, S, and Se)"],"prefix":"10.1002","volume":"24","author":[{"given":"Dhritabrata","family":"Pal","sequence":"first","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani  Pilani campus Vidya Vihar Rajasthan 333-031 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heena","family":"Charaya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani  Pilani campus Vidya Vihar Rajasthan 333-031 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1359-523X","authenticated-orcid":false,"given":"Shamik","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani  Pilani campus Vidya Vihar Rajasthan 333-031 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,6,20]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11224-019-01357-2"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-018-37186-2"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.97.19.10371"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0969-2126(99)80011-2"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M111.232876"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.R112.418574"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp020029k"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6MB00259E"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-2958.1991.tb00722.x"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1093\/jn\/130.7.1653"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0125220"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.9b02238"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP01508C"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemphys.2017.11.010"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.8b12200"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2860(82)87223-2"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4730909"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp00530d"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2121609"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2004.12.046"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp20727j"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemphys.2022.111451"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/b718656h"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.466432"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/qua.560100211"},{"key":"e_1_2_8_26_1","doi-asserted-by":"crossref","unstructured":"R.\u2005F. 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