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The catalysts were evaluated for degradation of ortho\u2010dichloro benzene (<jats:italic>o\u2010DCB<\/jats:italic>) in air\/helium, a representative probe molecule for polychlorinated dibenzo\u2010para\u2010dioxin and polychlorinated dibenzofuran by employing <jats:italic>in\u2005situ<\/jats:italic> Fourier\u2010transform infrared spectroscopy (FT\u2010IR spectroscopy). Different intermediate species formed on the surface of the TiO<jats:sub>2<\/jats:sub> supported catalysts through of interaction of sorbate molecules with the lattice and\/or gaseous oxygen were investigated in detail. Analysis of vibrational bands, observed during sorption of <jats:italic>o\u2010DCB<\/jats:italic> and <jats:italic>o\u2010DCB<\/jats:italic>\u2010air mixture as a function of temperature over these catalysts, delineated the role of surface intermediate species such as phenolate, enolates, maleates, carboxylates, carbonates in mineralization of <jats:italic>o\u2010DCB<\/jats:italic>. Nature and stability of intermediate species, found to be different over these catalysts, were able to elucidate the catalytic activity trend.<\/jats:p>","DOI":"10.1002\/cphc.202300472","type":"journal-article","created":{"date-parts":[[2024,3,15]],"date-time":"2024-03-15T05:38:38Z","timestamp":1710481118000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Role of Constituent Oxides for Thermal Mineralization of o\u2010Dichloro Benzene over Mixed\u2010Oxide\u2010TiO<sub>2<\/sub> Catalysts: A Mechanistic Explanation"],"prefix":"10.1002","volume":"25","author":[{"given":"Kaustava","family":"Bhattacharyya","sequence":"first","affiliation":[{"name":"Chemistry Division Bhabha Atomic Research Centre  Mumbai 400 085 India"},{"name":"Homi Bhabha National Institute  Mumbai 400 094 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adarsh","family":"Kumar","sequence":"additional","affiliation":[{"name":"Chemistry Division Bhabha Atomic Research Centre  Mumbai 400 085 India"},{"name":"Homi Bhabha National Institute  Mumbai 400 094 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Deepak","family":"Tyagi","sequence":"additional","affiliation":[{"name":"Chemistry Division Bhabha Atomic Research Centre  Mumbai 400 085 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. 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