{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T03:23:38Z","timestamp":1787801018072,"version":"build-2784847793"},"reference-count":49,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2023,11,13]],"date-time":"2023-11-13T00:00:00Z","timestamp":1699833600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2024,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Cr<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> was applied to study the modification of In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> based catalysts for CO<jats:sub>2<\/jats:sub> hydrogenation to methanol reaction. Combined with X\u2010ray diffraction (XRD), scanning transmission electron microscopy (STEM), X\u2010ray photoelectron spectroscopy (XPS), etc., the structure of the catalysts was characterized. The reaction performances for CO<jats:sub>2<\/jats:sub> hydrogenation to methanol were evaluated on a stainless\u2010steel fix\u2010bed reactor. The results showed that solid solutions were formed for the Cr<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> promoted In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> catalysts. The important role of electronic interaction between Cr<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> was revealed in the hydrogenation reaction. In<jats:sub>1.25<\/jats:sub>Cr<jats:sub>0.75<\/jats:sub>O<jats:sub>3<\/jats:sub> sample exhibited the highest methanol yield, which was 2.8 times higher than that of pure In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>. No deactivation was observed for In<jats:sub>1.25<\/jats:sub>Cr<jats:sub>0.75<\/jats:sub>O<jats:sub>3<\/jats:sub> sample during the 50\u2005hours of reaction. The improved catalytic performance may be due to the formation of the solid solutions and the highest amount of oxygen vacancies.<\/jats:p>","DOI":"10.1002\/cphc.202300530","type":"journal-article","created":{"date-parts":[[2023,10,22]],"date-time":"2023-10-22T22:34:58Z","timestamp":1698014098000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Cr<sub>2<\/sub>O<sub>3<\/sub> Promoted In<sub>2<\/sub>O<sub>3<\/sub> Catalysts for CO<sub>2<\/sub> Hydrogenation to Methanol"],"prefix":"10.1002","volume":"25","author":[{"given":"Yuying","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education &amp; Hubei Key Laboratory of Catalysis and Materials Science South-Central Minzu University  Wuhan 430074 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