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We suggest new chemical names for the 2D borane compounds and analyze the geometric and electronic structure carbon <jats:italic>vs<\/jats:italic>. boron comparatives by means of HOMO\u2010LUMO gaps, bonding schemes, electron density topological properties and predicted NMR chemical shifts. The predictions on the properties in planar hexagonal cyclic boranes may help in the design of synthesis procedures for these yet\u2010unkown compounds.<\/jats:p>","DOI":"10.1002\/cphc.202300809","type":"journal-article","created":{"date-parts":[[2024,1,26]],"date-time":"2024-01-26T14:05:14Z","timestamp":1706277914000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Towards 2D Borane Chemistry in Hexagonal Cyclic Compounds"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2554-631X","authenticated-orcid":false,"given":"Rub\u00e9n","family":"L\u00f3pez\u2010S\u00e1nchez","sequence":"first","affiliation":[{"name":"Instituto de Qu\u00edmica-F\u00edsica \u201cBlas Cabrera\u201d  CSIC E-28006 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7838-9974","authenticated-orcid":false,"given":"Maxime","family":"Ferrer","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica M\u00e9dica  CSIC E-28006 Madrid Spain"},{"name":"Theoretical Chemistry and Computational Modelling Doctoral School Universidad  Aut\u00f3noma de Madrid, E 28049 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9108-8615","authenticated-orcid":false,"given":"Josep M.","family":"Oliva\u2010Enrich","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica-F\u00edsica \u201cBlas Cabrera\u201d  CSIC E-28006 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6876-6211","authenticated-orcid":false,"given":"Ibon","family":"Alkorta","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica M\u00e9dica  CSIC E-28006 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9213-6858","authenticated-orcid":false,"given":"Jos\u00e9","family":"Elguero","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica M\u00e9dica  CSIC E-28006 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,2,15]]},"reference":[{"key":"e_1_2_9_1_1","volume-title":"Organic chemistry, 8th","author":"Brown W. 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