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As multi\u2010usage molecules, these compounds may be involved in sustainable chemistry processes such as the cold plasma techniques for which the generated electrons are known to be responsible for reactions. Therefore, it is desirable to explore the interaction of low energy electrons with the co\u2010compounds in the gas phase. The production of chlorine and cyanine anions, initiated by the electron collision with CCl<jats:sub>4<\/jats:sub> and BZN, respectively, undergo nucleophilic substitution S<jats:sub>N<\/jats:sub>2 reaction with the precursors molecules for the synthesis of chlorobenzene and tricholoacetonitrile. The mechanism of fragmentation of benzonitrile and the synthesis reactions are rationalized by DFT calculations. The yield of the cyanine anion produced from the ion reaction increases with the temperature of the admixture gas, probed in the 25\u2013100\u2009\u00b0C temperature range. The present work may contribute to a potential process for the production of chlorobenzene for instance via (cold) plasma techniques.<\/jats:p>","DOI":"10.1002\/cphc.202400287","type":"journal-article","created":{"date-parts":[[2024,6,25]],"date-time":"2024-06-25T08:03:33Z","timestamp":1719302613000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Low Energy (&lt;10\u2005eV) Electron Collision with Benzonitrile\u2010CCl<sub>4<\/sub> Admixture: A Combined Theoretical and Experimental Study"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9382-4310","authenticated-orcid":false,"given":"H.","family":"Abdoul\u2010Carime","sequence":"first","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1 Institut de Physique des 2 Infinis  CNRS\/IN2P3, UMR5822 F-69003 Lyon France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guillaume","family":"Thiam","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1, CNRS Institut Lumi\u00e8re Mati\u00e8re  UMR5306 F-69622 Villeurbanne France"},{"name":"Dipartimento di Chimica, Biologia e Biotecnologie Universit\u00e0 degli Studi di Perugia  Via Elce di Sotto, 8 06123 Perugia Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franck","family":"Rabilloud","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1, CNRS Institut Lumi\u00e8re Mati\u00e8re  UMR5306 F-69622 Villeurbanne France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,27]]},"reference":[{"key":"e_1_2_11_1_1","unstructured":"https:\/\/www.atamanchemicals.com\/benzonitrile_u27521\/ ATAMA Chemicals Company."},{"key":"e_1_2_11_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aao4890"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361\/202142206"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00862a014"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abb7535"},{"key":"e_1_2_11_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2004.11.019"},{"key":"e_1_2_11_7_1","unstructured":"1.5\u00d7104electrons per deposited 500\u2005keV. 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