{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T16:23:47Z","timestamp":1787243027682,"version":"build-2736575974"},"reference-count":124,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2024,8,5]],"date-time":"2024-08-05T00:00:00Z","timestamp":1722816000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121005"],"award-info":[{"award-number":["22121005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002338","name":"Ministry of Education of the People's Republic of China","doi-asserted-by":"publisher","award":["B12015"],"award-info":[{"award-number":["B12015"]}],"id":[{"id":"10.13039\/501100002338","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2024,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The pursuit of molecule\u2010based magnetic memory materials contributes significantly to high\u2010density information storage research in the frame of the ongoing information technologies revolution. Remarkable progress has been achieved in both transition metal (TM) and lanthanide based single\u2010molecule magnets (SMMs). Notably, six\u2010coordinated Co\n                    <jats:sup>II<\/jats:sup>\n                    SMMs hold particular research significance owing to the economic and abundant nature of 3\n                    <jats:italic>d<\/jats:italic>\n                    TM ions compared to lanthanide ions, the substantial spin\u2010orbit coupling of Co\n                    <jats:sup>II<\/jats:sup>\n                    ions, the potential for precise control over coordination geometry, and the air\u2010stability of coordination\u2010saturated structures. In this review, we will summarize the progress made in six\u2010coordinated Co\n                    <jats:sup>II<\/jats:sup>\n                    SMMs, organized by their coordination geometry and molecular structure similarity. Valuable insights, principles, and new mechanism gleaned from this research and remaining issues that need to be addressed will also be discussed to guide future optimization.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202400396","type":"journal-article","created":{"date-parts":[[2024,6,18]],"date-time":"2024-06-18T14:33:52Z","timestamp":1718721232000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Six\u2010Coordinated Co\n                    <sup>II<\/sup>\n                    Single\u2010Molecule Magnets: Synthetic Strategy, Structure and Magnetic Properties"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5664-1374","authenticated-orcid":false,"given":"Mengmeng","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences Molecular Chemistry Materials and Catalysis (IMCN\/MOST) Universit\u00e9 catholique de Louvain  1348 Louvain-la-Neuve Belgium"},{"name":"Key Laboratory of Advanced Energy Materials Chemistry (MOE) and Frontiers Science Center for New Organic Matter College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongsu","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Energy Materials Chemistry (MOE) and Frontiers Science Center for New Organic Matter College of Chemistry Nankai University  Tianjin 300071 China"},{"name":"Department of Chemistry Texas A&amp;M University  College Station, Texas 77843 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yann","family":"Garcia","sequence":"additional","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences Molecular Chemistry Materials and Catalysis (IMCN\/MOST) Universit\u00e9 catholique de Louvain  1348 Louvain-la-Neuve Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0396-1846","authenticated-orcid":false,"given":"Peng","family":"Cheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Energy Materials Chemistry (MOE) and Frontiers Science Center for New Organic Matter College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,5]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00058a027"},{"key":"e_1_2_7_2_1","volume-title":"Molecular Nanomagnets","author":"Gatteschi D.","year":"2007"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213984"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353352"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601467"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/B714715E"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja029629n"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00222"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705761"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02638"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c01299"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja200198v"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC00582K"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav0652"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abl5470"},{"key":"e_1_2_7_16_1","volume-title":"Lanthanides: Fundamentals and Applications","author":"Cheng P.","year":"2023"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1630"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.06.013"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c02401"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214871"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b00632"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202003211"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT03903B"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms10467"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01073"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002673"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC02611C"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03781K"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC01909A"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11043"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat7319"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14620"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC01155C"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI01267J"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5300"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00706-022-02920-0"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527690541"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.03.001"},{"key":"e_1_2_7_39_1","volume-title":"Coordination Chemistry","author":"Gispert J. R.","year":"2008"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00439F"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/430_022"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic701365t"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23234"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.03.114"},{"key":"e_1_2_7_45_1","volume-title":"Ligand Field Theory and its Applications, 1st ed","author":"Figgis B. N.","year":"2000"},{"key":"e_1_2_7_46_1","volume-title":"Electron Paramagnetic Resonance of Transition Ions","author":"Abragam A.","year":"1970"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1142\/4870"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1093\/oso\/9780199298624.001.0001"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1007\/b12224"},{"key":"e_1_2_7_50_1","volume-title":"Modern Quantum Chemistry: Introduction to Advanced Electronic Structure Theory","author":"Szabo A.","year":"2012"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00001B"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00266A"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2SC20801F"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC06041H"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3075314"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic401057f"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304386"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4015138"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/b807074a"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic4029047"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b05739"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00447"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201900219"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.6b02091"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00275B"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202301693"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC01172E"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02692"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00950"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP03157A"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc21893g"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b00526"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT00770A"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c07552"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC02035F"},{"key":"e_1_2_7_76_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b00055"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC04756A"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja035478s"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1039\/B403524K"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.79.1372"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202001148"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic500916u"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT04651K"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03238G"},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2018.05.006"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201801026"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b00543"},{"key":"e_1_2_7_88_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT04592A"},{"key":"e_1_2_7_89_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT00595B"},{"key":"e_1_2_7_90_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00257G"},{"key":"e_1_2_7_91_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT00979D"},{"key":"e_1_2_7_92_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c00034"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b01719"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03992A"},{"key":"e_1_2_7_95_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201600481"},{"key":"e_1_2_7_96_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QI01373J"},{"key":"e_1_2_7_97_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201402955"},{"key":"e_1_2_7_98_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02743"},{"key":"e_1_2_7_99_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT04274B"},{"key":"e_1_2_7_100_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02287"},{"key":"e_1_2_7_101_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT02131C"},{"key":"e_1_2_7_102_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT00096E"},{"key":"e_1_2_7_103_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00531"},{"key":"e_1_2_7_104_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT04065G"},{"key":"e_1_2_7_105_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2018.04.003"},{"key":"e_1_2_7_106_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01473"},{"key":"e_1_2_7_107_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01554F"},{"key":"e_1_2_7_108_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09435B"},{"key":"e_1_2_7_109_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT04339G"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.11.012"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702099"},{"key":"e_1_2_7_112_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b00864"},{"key":"e_1_2_7_113_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic400073y"},{"key":"e_1_2_7_114_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT03574G"},{"key":"e_1_2_7_115_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC04461H"},{"key":"e_1_2_7_116_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic5029299"},{"key":"e_1_2_7_117_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC02234K"},{"key":"e_1_2_7_118_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201600569"},{"key":"e_1_2_7_119_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01651"},{"key":"e_1_2_7_120_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02324"},{"key":"e_1_2_7_121_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NJ01236A"},{"key":"e_1_2_7_122_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT02070E"},{"key":"e_1_2_7_123_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc16430b"},{"key":"e_1_2_7_124_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT02559E"}],"container-title":["ChemPhysChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.202400396","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T21:51:45Z","timestamp":1760392305000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cphc.202400396"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,8,5]]},"references-count":124,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2024,9,16]]}},"alternative-id":["10.1002\/cphc.202400396"],"URL":"https:\/\/doi.org\/10.1002\/cphc.202400396","archive":["Portico"],"relation":{},"ISSN":["1439-4235","1439-7641"],"issn-type":[{"value":"1439-4235","type":"print"},{"value":"1439-7641","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,8,5]]},"assertion":[{"value":"2024-04-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-08-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202400396"}}