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Prototype Lewis acid CF\n                    <jats:sub>3<\/jats:sub>\n                    I is placed above the planes of benzene, naphthalene, anthracene, phenanthrene, naphthacene, chrysene, triphenyl, pyrene, and coronene. The I atom positions itself some 3.3\u20133.4\u2005\u00c5 above the polycyclic plane, and the associated interaction energy is about 4\u2005kcal\/mol. This quantity is a little smaller for benzene, but is roughly equal for the larger polycyclics. The energy only oscillates a little as the Lewis acid slides across the face of the polycyclic, preferring regions of higher \u03c0\u2010electron density over minima of the electrostatic potential. The binding is dominated by dispersion which contributes half of the total interaction energy.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202400482","type":"journal-article","created":{"date-parts":[[2024,6,26]],"date-time":"2024-06-26T10:13:16Z","timestamp":1719396796000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Halogen Bonding to the \u03c0\u2010Systems of Polycyclic Aromatics"],"prefix":"10.1002","volume":"25","author":[{"given":"Akhtam","family":"Amonov","sequence":"first","affiliation":[{"name":"Department of Optics and Spectroscopy Institute of Engineering Physics Samarkand State University  University blv. 15 140104 Samarkand Uzbekistan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0793-0369","authenticated-orcid":false,"given":"Steve","family":"Scheiner","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  Logan, Utah 84322-0300 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,15]]},"reference":[{"key":"e_1_2_8_1_1","volume-title":"The Hydrogen Bond","author":"Pimentel G. 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