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However, sulfide solid electrolytes are limited by the generation of toxic hydrogen sulfide and conductivity deterioration upon moisture exposure. Although numerous studies have investigated the hydrolysis degradation induced by \u201cmoisture,\u201d the influence of \u201catmospheric gases\u201d during moisture exposure has not been extensively investigated despite the importance for practical fabrication. Therefore, in this study, we investigated the impact of atmospheric gases during moisture exposure on an argyrodite\u2010type Li<jats:sub>6<\/jats:sub>PS<jats:sub>5<\/jats:sub>Cl via electrochemical impedance spectroscopy, X\u2010ray diffraction, X\u2010ray absorption spectroscopy, and X\u2010ray photoelectron spectroscopy. The electrolyte powder was exposed to various atmospheric gases, namely Ar, Ar+500\u2005ppm CO<jats:sub>2<\/jats:sub>, O<jats:sub>2<\/jats:sub>, and O<jats:sub>2<\/jats:sub>+500\u2005ppm CO<jats:sub>2<\/jats:sub>, with moisture at a dew point of \u221220\u2009\u00b0C, and H<jats:sub>2<\/jats:sub>S gas generation was monitored. As a result, the amount of H<jats:sub>2<\/jats:sub>S gas did not depend on the atmospheric gases. However, the atmospheric gases had a significant effect on the decrease in conductivity. Spectroscopic analyses revealed that CO<jats:sub>2<\/jats:sub> facilitates the formation of carbonates and that O<jats:sub>2<\/jats:sub> promotes the formation of phosphates and sulfonates. The formation of these compounds leads to surface degradation, which further decreases the conductivity.<\/jats:p>","DOI":"10.1002\/cphc.202400872","type":"journal-article","created":{"date-parts":[[2024,10,30]],"date-time":"2024-10-30T12:35:55Z","timestamp":1730291755000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Influence of Atmospheric Gas Species on an Argyrodite\u2010Type Sulfide Solid Electrolyte During Moisture Exposure"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6973-7786","authenticated-orcid":false,"given":"Yusuke","family":"Morino","sequence":"first","affiliation":[{"name":"Murata Manufacturing Co., Ltd.  1-10-1 Higashikotari Nagaokakyo-shi, Kyoto 617-8555 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