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The alkene + ozone reaction (alkene ozonolysis) forms a carbonyl oxide \u2013 a Criegee intermediate (CI). CIs are interesting from an atmospheric chemistry perspective. They are implicated in enhancing the oxidizing capacity of the troposphere and in secondary organic aerosol formation. CIs may participate in bimolecular reactions with trace atmospheric vapors like water and methanol. Here, the chemistry of the two isomers of CFHOO and of CF\n                    <jats:sub>3<\/jats:sub>\n                    CHOO with water, water dimer, and methanol is explored. The present study confirms that the\n                    <jats:italic>syn<\/jats:italic>\n                    \u2010conformer is the minimum energy structure for both CIs and that the reactions of\n                    <jats:italic>anti<\/jats:italic>\n                    \u2010CFHOO display slightly lower activation energies cf.\n                    <jats:italic>syn<\/jats:italic>\n                    \u2010CFHOO, thus promoting faster reaction. For both\n                    <jats:italic>syn<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>anti<\/jats:italic>\n                    \u2010CFHOO, the energy barrier in the pathway to adding water, water dimer, or methanol is lower\u2014and the overall reaction exoergicity greater\u2014than for the corresponding reactions involving the nonfluorinated analogue, CH\n                    <jats:sub>2<\/jats:sub>\n                    OO. The corresponding bimolecular reaction rates are thus predicted to be faster for CFHOO than CH\n                    <jats:sub>2<\/jats:sub>\n                    OO. Similar reactivity trends are found when comparing the same reactions of\n                    <jats:italic>syn<\/jats:italic>\n                    \u2010CF\n                    <jats:sub>3<\/jats:sub>\n                    CHOO, cf.\n                    <jats:italic>syn<\/jats:italic>\n                    \u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    CHOO, but not when comparing the energetics of the reactions involving anti\u2010CF\n                    <jats:sub>3<\/jats:sub>\n                    CHOO\n                    <jats:italic>cf<\/jats:italic>\n                    .\n                    <jats:italic>anti<\/jats:italic>\n                    \u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    CHOO.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202401023","type":"journal-article","created":{"date-parts":[[2025,9,14]],"date-time":"2025-09-14T23:19:52Z","timestamp":1757891992000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Unraveling Electronic Effects that Influence the Bimolecular Chemistry of Fluorinated Criegee Intermediates"],"prefix":"10.1002","volume":"26","author":[{"given":"Lily M.","family":"Guidry","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Louisiana at Lafayette  Lafayette LA 70504 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Courtney A.","family":"Poirier","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Louisiana at Lafayette  Lafayette LA 70504 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aylin","family":"Yigiter","sequence":"additional","affiliation":[{"name":"St. Thomas More Catholic High School  Lafayette LA 70508 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Teagan P.","family":"Legg","sequence":"additional","affiliation":[{"name":"Department of Chemistry Coastal Carolina University  Conway SC 29526 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Barbara","family":"Marchetti","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Louisiana at Lafayette  Lafayette LA 70504 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael N. 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