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The results show that Ag<jats:sub>6<\/jats:sub>Ru exhibits an electron\u2010precise ten\u2010electron 1S<jats:sup>2<\/jats:sup>1P1D planar superatomic electron shell structure, related to the 1S<jats:sup>2<\/jats:sup>1P<jats:sup>6<\/jats:sup>1D<jats:sup>10<\/jats:sup> 18\u2010electron structure of the spherical Ag<jats:sub>10<\/jats:sub>Ru cluster, involving seven and ten reactive sites. The favorable electronic structure in such related clusters exhibits diatropic ring currents and long\u2010range shielded regions, supporting the respective planar\u2010 and 3D aromatic character. Hence, further planar and 3D relationship between electron precise clusters may trigger a fundamental rationalization in finding stable and useful targets for undergoing catalytic activity for reactions such as oxygen reduction reaction, extending similarities between different cluster shapes at certain sizes.<\/jats:p>","DOI":"10.1002\/cphc.202401118","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T00:11:29Z","timestamp":1741738289000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Evaluating Aromaticity in Ag<sub>6<\/sub>Ru and Ag<sub>10<\/sub>Ru as Electron\u2010Precise Superatom Clusters"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7579-0607","authenticated-orcid":false,"given":"Mes\u00edas","family":"Orozco\u2010Ic","sequence":"first","affiliation":[{"name":"Instituto de Ciencias F\u00edsicas Universidad Nacional Aut\u00f3noma de M\u00e9xico  Cuernavaca 62210 M\u00e9xico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2373-7729","authenticated-orcid":false,"given":"Peter L.","family":"Rodr\u00edguez\u2010Kessler","sequence":"additional","affiliation":[{"name":"Centro de Investigaciones en \u00d3ptica A.C.  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