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To manipulate their chemical properties and interfacial characteristics, a wide range of substrates needs to be employed for the formation of self\u2010assemblies. Research has, however, predominantly focused on the Au(111) substrate. Herein, a systematic approach is presented for producing long\u2010range, densely packed self\u2010assemblies using carbenes deposited over (111) and (100) crystalline facets of gold and silver single crystals. Atomic\u2010resolution characterization with scanning tunneling microscopy (performed at 78\u2009K and room temperature) is combined with the molecular structure, showing the role of distinct crystal facets in the ordering of self\u2010assembled monolayers.<\/jats:p>","DOI":"10.1002\/cphc.202500227","type":"journal-article","created":{"date-parts":[[2025,7,2]],"date-time":"2025-07-02T13:03:18Z","timestamp":1751461398000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Surface Characterization of N\u2010Heterocyclic Carbenes on Gold and Silver: Exploring Distinct Crystalline Facets"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7332-196X","authenticated-orcid":false,"given":"Sayantan","family":"Mahapatra","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Illinois Chicago  Chicago Illinois 60607 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