{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T16:11:07Z","timestamp":1789661467099,"version":"4.0.1"},"reference-count":39,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T00:00:00Z","timestamp":1770681600000},"content-version":"vor","delay-in-days":9,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,1]],"date-time":"2026-02-01T00:00:00Z","timestamp":1769904000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:p>\n                    This study investigates the Bi(III) ions electroreduction in aqueous chlorate(VII) and aqueous\u2010ethanolic chlorate(VII)\u2010supporting electrolytes (SE) in the presence of the anionic surfactant sodium 1\u2010octanesulfonate (1OSASS) over a range of temperatures. Electrochemical techniques, including direct current (DC) polarography, cyclic voltammetry (CV), and square\u2010wave voltammetry (SWV), were used to evaluate both kinetic and thermodynamic parameters. Increasing ethanol concentration led to a decrease in the standard heterogeneous electron transfer rate constant (\n                    <jats:italic>k<\/jats:italic>\n                    <jats:sub>s<\/jats:sub>\n                    ), despite an increase in the diffusion coefficient of the oxidised species (\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>ox<\/jats:sub>\n                    ). Rising temperature and surfactant concentration caused a shift in the formal potential (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>f<\/jats:sub>\n                    <jats:sup>0<\/jats:sup>\n                    ) and an increase in redox peak separation (\u0394\n                    <jats:italic>E<\/jats:italic>\n                    ), indicating reduced process reversibility. Activation parameters, including activation energy (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    ), enthalpy (\u0394\n                    <jats:italic>H<\/jats:italic>\n                    <jats:sup>0<\/jats:sup>\n                    ), entropy (\u0394\n                    <jats:italic>S<\/jats:italic>\n                    <jats:sup>0<\/jats:sup>\n                    ), and Gibbs free energy (\u0394\n                    <jats:italic>G<\/jats:italic>\n                    <jats:sup>0<\/jats:sup>\n                    ), were determined using the Arrhenius and Eyring equations. The results confirm that 1OSASS exhibits a \u2018cap\u2010pair\u2019 effect, likely due to competitive adsorption and complexation, significantly affecting redox kinetics. Overall, the study highlights the complex influence of the solvent\u2013surfactant system on the structure of the electrical double layer (EDL) and on the kinetics and mechanism of the Bi(III) ions electroreduction process.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202500518","type":"journal-article","created":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T17:48:33Z","timestamp":1770745713000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Bi(III) Ion Electroreduction in the Presence of Ethanol and Sodium 1\u2010Octanesulfonate at a Thin\u2010Layer Amalgam Electrode (Renewable Liquid Silver Amalgam Film Electrode); Kinetic and Thermodynamic Aspects"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-4098-5671","authenticated-orcid":false,"given":"Alicja Natalia","family":"Pawlak","sequence":"first","affiliation":[{"name":"Department of Analytical Chemistry Institute of Chemical Sciences Faculty of Chemistry Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9851-9438","authenticated-orcid":false,"given":"Agnieszka","family":"Nosal\u2010Wierci\u0144ska","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry Institute of Chemical Sciences Faculty of Chemistry Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,10]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/wnan.1801"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/pharmaceutics13111793"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1179\/1743280412Y.0000000010"},{"key":"e_1_2_7_5_1","first-page":"4100","article-title":"Nanolayered Bismuth Oxyselenide for Field\u2010Effect Transistors and Photodetectors","volume":"8","author":"Liu H.","year":"2025","journal-title":"American Chemical Society"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.135652"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29174062"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-14914-9"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.05.124"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.04.103"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26010117"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(78)80065-5"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12678-019-00548-z"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(69)90266-0"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10008-011-1337-4"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2220728"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13204-023-02778-6"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2007.04.002"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2009.07.008"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26133972"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/ac035d"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac199163121705"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(75)80345-7"},{"key":"e_1_2_7_24_1","unstructured":"United States Pharmacopeial Convention (USP) \u201cMonograph c801\u201d. In USP 32\u2013NF 27. Can Be Found under 2009 Available at:https:\/\/www.drugfuture.com\/pharmacopoeia\/usp32\/pub\/data\/v32270\/usp32nf27s0_c801.html(accessed: 12 VII 2025)."},{"key":"e_1_2_7_25_1","volume-title":"Elektroanalityczne Metody Wyznaczania Sta\u0142ych Fizykochemicznych","author":"Galus Z.","year":"1979"},{"key":"e_1_2_7_26_1","first-page":"338","volume-title":"Physical Chemistry for the Biosciences","author":"Chang R.","year":"2005"},{"key":"e_1_2_7_27_1","unstructured":"\u201cTransition State Theory: Eyring Equation\u201d LibreTexts Chemistry Can Be Found under (accessed: 12 VII 2025) Available at:https:\/\/chem.libretexts.org\/\u2026\/Eyring_equation."},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100562a007"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c00332"},{"key":"e_1_2_7_30_1","first-page":"238","article-title":"Solvent Effect on the Enthalpy and Entropy of Activation for the Hydrolysis of Ethyl Cinnamate in Mixed Solvent System","volume":"7","author":"Singh A. K.","year":"2017","journal-title":"Journal of Physical Chemistry Biophysics"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-biophys-083012-130318"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.5b09925"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed050p331"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.4c06270"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29153455"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/elan.201800852"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29214986"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.3390\/electrochem3040052"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2005.09.004"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00535F"}],"container-title":["ChemPhysChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.202500518","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cphc.202500518","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.202500518","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T14:20:06Z","timestamp":1771338006000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cphc.202500518"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2]]},"references-count":39,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/cphc.202500518"],"URL":"https:\/\/doi.org\/10.1002\/cphc.202500518","archive":["Portico"],"relation":{},"ISSN":["1439-4235","1439-7641"],"issn-type":[{"value":"1439-4235","type":"print"},{"value":"1439-7641","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2]]},"assertion":[{"value":"2025-07-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-23","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500518"}}