{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T06:26:59Z","timestamp":1773037619714,"version":"3.50.1"},"reference-count":68,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378185"],"award-info":[{"award-number":["22378185"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2026,2,25]]},"abstract":"<jats:p>\n                    Isolated monolayer graphene can be coupled with silica (SiO\n                    <jats:sub>2<\/jats:sub>\n                    ) as graphene\u2010based nanoelectronic devices. The fabricated heterojunction composites in moist environments have been involved in environmental monitoring, optical detection, and health sensors. However, the corresponding interfacial stability and structures between graphene and silica substrates remain unexplored. Herein, molecular simulations were applied to investigate the adhesion of graphene\/SiO\n                    <jats:sub>2<\/jats:sub>\n                    composite interfaces in water media. Different SiO\n                    <jats:sub>2<\/jats:sub>\n                    surface types and varied SiO\n                    <jats:sub>2<\/jats:sub>\n                    hydrophilicity degrees were considered. The thermodynamic free energy was simulated to characterize the interfacial interaction. The required energetic barriers associated with the graphene detachment can be determined. SiO\n                    <jats:sub>2<\/jats:sub>\n                    substrates possess differential surface affinity toward graphene. The connection between the adhesion strength and the substrate types was established. Under higher hydrophilic conditions, the attached graphene sheet can easily be separated from the silica substrates. This behavior cannot be observed in dry conditions, which is attributed to competitive actions between the interfacial hydration force and the substrate interaction. The morphologic transformations and hydration structures of the graphene\u2010silica interface with intervening water layers were also characterized, which is critical in modulating the interface stability. Our simulation results provide new microscopic insights into the interfacial states and structures of graphene\u2010SiO\n                    <jats:sub>2<\/jats:sub>\n                    systems in an aqueous environment.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202500643","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T16:07:09Z","timestamp":1772986029000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Stability and Confined Structures for Graphene\/SiO\n                    <sub>2<\/sub>\n                    Composites in Water Media"],"prefix":"10.1002","volume":"27","author":[{"given":"Wei","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials\u2010Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University  Nanjing 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