{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T11:40:06Z","timestamp":1787658006219,"version":"build-2736575974"},"reference-count":48,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,5,20]],"date-time":"2026-05-20T00:00:00Z","timestamp":1779235200000},"content-version":"vor","delay-in-days":6,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T00:00:00Z","timestamp":1778716800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22172055"],"award-info":[{"award-number":["22172055"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003453","name":"Natural Science Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2026A1515010946"],"award-info":[{"award-number":["2026A1515010946"]}],"id":[{"id":"10.13039\/501100003453","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2026,5,14]]},"abstract":"<jats:p>\n                    Alkyl side chains of molecules play a crucial role in molecular self\u2010assembly on highly oriented pyrolytic graphite (HOPG), and their symmetry serves as a determinant factor in controlling the self\u2010assembled patterns. Herein, the self\u2010assembly behaviors of TPTD\u2010Nap1 bearing symmetric side chains and TPTD\u2010Nap2 with asymmetric side chains were investigated at the liquid\/solid interface by scanning tunneling microscopy (STM). At the 1\u2010octanoic acid\/HOPG interface, TPTD\u2010Nap1 self\u2010assembled into a large\u2010scale linear structure accompanied by a small fraction of zigzag structure, whereas TPTD\u2010Nap2 exclusively formed a zigzag structure. In contrast to the self\u2010assembled polymorphism TPTD\u2010Nap1 at the\n                    <jats:italic>n<\/jats:italic>\n                    \u2010tetradecane\/HOPG interface, TPTD\u2010Nap2 self\u2010assembled into only one type of zigzag structure. We found that shape complementarity and dipole\u2013dipole interactions between the conjugated cores thermodynamically favored the antiparallel packing of these molecules, and the selective interdigitation of asymmetrical side chains restricted the self\u2010assembled structural polymorphism of TPTD\u2010Nap2. Consequently, tailoring the side\u2010chain symmetry emerges as a promising strategy for regulating the self\u2010assembly of conjugated molecules with well\u2010defined geometries.\n                  <\/jats:p>","DOI":"10.1002\/cphc.202500891","type":"journal-article","created":{"date-parts":[[2026,5,20]],"date-time":"2026-05-20T07:16:11Z","timestamp":1779261371000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Side\u2010Chain Symmetry Effect on Self\u2010Assembled Structures of Thienophenanthrene Derivatives"],"prefix":"10.1002","volume":"27","author":[{"given":"Yue","family":"Huang","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering South China University of Technology  Guangzhou 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