{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T21:58:32Z","timestamp":1785362312042,"version":"3.55.0"},"reference-count":38,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22308341"],"award-info":[{"award-number":["22308341"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:p>\n                    In order to enhance the light absorption capacity and promote the interlayer electron transport of CoAl\u2010layered double hydroxides (CoAl\u2010LDHs), a composite material of Zinc tetrakis (4\u2010carboxyphenyl) porphyrin (ZnTCPP) intercalated into CoAl\u2010LDHs interlayer was prepared by the exfoliation and re\u2010stacking method. The optimized composite exhibited excellent performance toward photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to CO, with an average CO evolution rate of 57.2\u2009\u03bcmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which was 5.84 times and 2.87 times higher than those of pristine CoAl\u2010LDHs (9.8\u2009\u03bcmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and ZnTCPP (19.9\u2009\u03bcmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), respectively. It is found that the intercalated ZnTCPP in CoAl\u2010LDHs could greatly improve the light absorption capacity and promote the interlayer electron transport, resulting in high photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction performance.\n                  <\/jats:p>","DOI":"10.1002\/cphc.70515","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T21:14:02Z","timestamp":1784582042000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Zinc Tetrakis (4\u2010Carboxyphenyl) Porphyrin Intercalation Modification in CoAl\u2010Layered Double Hydroxides for Efficient Photocatalytic Reduction of CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"27","author":[{"given":"Taihua","family":"Lu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucheng","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8371-6244","authenticated-orcid":false,"given":"Jiawei","family":"Ye","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tielin","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1528-1955","authenticated-orcid":false,"given":"Jun","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology  Wuhan P. R. 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