{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T05:05:07Z","timestamp":1789275907222,"version":"build-2803163510"},"reference-count":85,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2026,9,14]]},"abstract":"<jats:p>\n                    In this study, poly(urethane methacrylate) (PUM)\u2013lignin (Lig) polymeric adsorbent in the form of microspheres was synthesized and evaluated for the removal of metal ions such as Cu(II), Ni(II), Zn(II), and C.I. Basic Yellow 40 (BY40) dye from aqueous solutions. The performance of the PUM adsorbent without lignin was also described. PUM and PUM\u2013Lig were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TG), attenuated total reflectance Fourier transform infrared spectroscopy (ATR\/FT\u2010IR), scanning electron microscopy (SEM) and X\u2010ray photoelectron spectroscopy (XPS), to confirm the successful incorporation of lignin and to assess their thermal stability, chemical structure, morphology, and surface properties. Equilibrium uptake of Cu(II), Ni(II), Zn(II), and BY40 was described by the Freundlich isotherm model rather than the Langmuir, Temkin, or Dubinin\u2013Radushkevich ones with the following affinity: Cu(II)\u2009&gt;\u2009Zn(II)\u2009&gt;\u2009BY40\u2009&gt;\u2009Ni(II). The experimental equilibrium sorption capacities ranged from 78.0 to 152.2\u2009mg\/g. The effect of NaCl, Na\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4,<\/jats:sub>\n                    and surfactants CTAB, TX100 on Cu(II), Ni(II), Zn(II), and BY40 was investigated. The effective desorption of Cu(II) and BY40 from adsorbents was performed using 1\u2009M HCl, 1\u2009M H\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4<\/jats:sub>\n                    , 1\u2009M HNO\n                    <jats:sub>3,<\/jats:sub>\n                    and 1\u2009M HCl or 1\u2009M NaCl in 50% v\/v methanol.\n                  <\/jats:p>","DOI":"10.1002\/cphc.70558","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T05:45:07Z","timestamp":1789105507000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Poly(urethane Methacrylate)\u2013Lignin (PUM\u2013Lig) Microspheres: Synthesis, Characterization, and Their Application in Metal Ions and Dye Adsorption"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5697-6075","authenticated-orcid":false,"given":"Monika","family":"Wawrzkiewicz","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry Faculty of Chemistry Institute of Chemical Sciences Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beata","family":"Podko\u015bcielna","sequence":"additional","affiliation":[{"name":"Department of Polymer Chemistry Faculty of Chemistry Institute of Chemical Sciences Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5451-4523","authenticated-orcid":false,"given":"Anna","family":"Wo\u0142owicz","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry Faculty of Chemistry Institute of Chemical Sciences Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bogdan","family":"Tarasiuk","sequence":"additional","affiliation":[{"name":"Department of Polymer Chemistry Faculty of Chemistry Institute of Chemical Sciences Maria Curie\u2010Sklodowska University  Lublin Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,10]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2022.116838"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-024-59612-4"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.133763"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2025.119080"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2020.137222"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0960-8524(00)00080-8"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1MA00354B"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2025.122751"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2024.119440"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-024-58061-3"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA00723E"},{"key":"e_1_2_9_13_1","first-page":"225","volume-title":"Singh in Advances in Biological Treatment of Industrial Waste Water and Their Recycling for a Sustainable Future","author":"Singh R. P.","year":"2019"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2021.130881"},{"key":"e_1_2_9_15_1","first-page":"42","article-title":"Water Purification: Physical, Mechanical, Chemical and Biological Treatments","volume":"8","author":"Trifir\u00f2 F.","year":"2024","journal-title":"Mediterranean Journal of Physical Sciences"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.epm.2024.12.003"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.135146"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.3390\/w17152335"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2024.121807"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2022.129596"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym14091890"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/pen.24883"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.reactfunctpolym.2021.105153"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2021.123432"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA13158E"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2019.02.042"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10965-025-04540-8"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00396-021-04843-4"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25225247"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2020.109610"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4RA05269B"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2MA00320A"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.121932"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.reactfunctpolym.2003.11.015"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/pi.5306"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2025.127262"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.125960"},{"key":"e_1_2_9_38_1","first-page":"637","article-title":"Urethane\u2010Acrylates as Main Components of Lacquers for Protective Coating of Some Materials","volume":"354","author":"Tarasiuk B.","year":"2000","journal-title":"Molecular Crystals and Liquid Crystals"},{"key":"e_1_2_9_39_1","first-page":"11","article-title":"UV\u2010Curable Urethane Methacrylates: Synthesis and Properties of Polymeric Protective Coatings for Glass Fibres","volume":"5","author":"Tarasiuk B.","year":"2003","journal-title":"Polish Journal of Chemical Technology"},{"key":"e_1_2_9_40_1","first-page":"95","article-title":"The Influence of Soft Segment on the Properties of UV\u2010Curable Urethane Methacrylates","volume":"8","author":"Tarasiuk B.","year":"2006","journal-title":"Polish Journal of Chemical Technology"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.24163"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10973-010-1184-z"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1515\/hf-2014-0265"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2018.09.186"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2024.1496901"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42247-021-00311-5"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2023.102973"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2004.04.022"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.153681"},{"key":"e_1_2_9_50_1","volume-title":"The XPS of Polymers Database","author":"Beamson G.","year":"2000"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00039a018"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elspec.2014.07.003"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2013.11.040"},{"key":"e_1_2_9_54_1","unstructured":"XPS Fitting \u201cOxygen\u201d XPS Fitting Database(2000)."},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0871412jes"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.7b04104"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b09950"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2025.137814"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2023.140801"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1155\/2016\/4627929"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jwpe.2019.100964"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA12723E"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14164702"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1098\/rsos.201485"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122156"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.51244\/IJRSI.2025.120500019"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-023-29098-0"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jes.2020.08.021"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-025-3536-y"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2021.151334"},{"key":"e_1_2_9_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2024.130347"},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2007.05.065"},{"key":"e_1_2_9_73_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2004.04.002"},{"key":"e_1_2_9_74_1","first-page":"220","article-title":"Lignin\u2010Based Biosorbents for Metal Ions: A Review of Recent Advances and Future Prospects","volume":"307","author":"Tran H. N.","year":"2017","journal-title":"Chemical Engineering Journal"},{"key":"e_1_2_9_75_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-981-95-3775-4_8"},{"key":"e_1_2_9_76_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym12112465"},{"key":"e_1_2_9_77_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2025.146480"},{"key":"e_1_2_9_78_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.clce.2025.100213"},{"key":"e_1_2_9_79_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2019.121174"},{"key":"e_1_2_9_80_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2020.02.047"},{"key":"e_1_2_9_81_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2017.08.016"},{"key":"e_1_2_9_82_1","doi-asserted-by":"publisher","DOI":"10.3390\/w13030385"},{"key":"e_1_2_9_83_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2024.103196"},{"key":"e_1_2_9_84_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10529-019-02650-0"},{"key":"e_1_2_9_85_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA06693G"},{"key":"e_1_2_9_86_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2025.140356"}],"container-title":["ChemPhysChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.70558","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cphc.70558","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cphc.70558","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T04:26:29Z","timestamp":1789273589000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cphc.70558"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,10]]},"references-count":85,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2026,9,14]]}},"alternative-id":["10.1002\/cphc.70558"],"URL":"https:\/\/doi.org\/10.1002\/cphc.70558","archive":["Portico"],"relation":{},"ISSN":["1439-4235","1439-7641"],"issn-type":[{"value":"1439-4235","type":"print"},{"value":"1439-7641","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,10]]},"assertion":[{"value":"2026-02-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-20","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70558"}}