{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T10:56:13Z","timestamp":1772794573732,"version":"3.50.1"},"reference-count":45,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2013,7,2]],"date-time":"2013-07-02T00:00:00Z","timestamp":1372723200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2013,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>[Sn<jats:sub>6<\/jats:sub>(O)<jats:sub>4<\/jats:sub>(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>] and [{Sn(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>] have been used to deposit SnO thin films by chemical vapour deposition. Films derived from [Sn<jats:sub>6<\/jats:sub>(O)<jats:sub>4<\/jats:sub>(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>] comprise uniform cubes and are highly oriented, whereas those deposited from [{Sn(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>] are made up of a continuous non\u2010oriented layer with oriented cubes on the surface. The structure of a co\u2010crystal, 2\u2009Sn<jats:sub>6<\/jats:sub>(O)<jats:sub>4<\/jats:sub>(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub><jats:bold>\u22c5<\/jats:bold>[Sn(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub><jats:bold>\u22c5<\/jats:bold>4\u2009THF, shows that [{Sn(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>], a liquid at room temperature, adopts a \u03bc\u2010OSiMe<jats:sub>3<\/jats:sub>\u2010bridged dimeric structure. [Sn<jats:sub>6<\/jats:sub>(O)<jats:sub>4<\/jats:sub>(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>] reacts with O<jats:sub>2<\/jats:sub> in a controlled manner to afford the novel oxo\u2010cluster [Sn<jats:sub>4(<\/jats:sub>O)(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>8<\/jats:sub>], the structure of which is reported. In addition, a crystal of {[Sn<jats:sub>4<\/jats:sub>(O)(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>5<\/jats:sub>]<jats:sup>+<\/jats:sup><jats:sub>2<\/jats:sub>[Sn(O)(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>Cl]<jats:sup>+<\/jats:sup><jats:sub>2<\/jats:sub>}[Cl]<jats:sup>\u2212<\/jats:sup><jats:sub>4<\/jats:sub> has been fortuitously isolated from the presence of SnCl<jats:sub>2<\/jats:sub> in the starting material for the preparation of [Sn<jats:sub>6<\/jats:sub>(O)<jats:sub>4<\/jats:sub>(OSiMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>], and has been shown to incorporate two novel cationic oxo\u2013tin clusters.<\/jats:p>","DOI":"10.1002\/cplu.201300104","type":"journal-article","created":{"date-parts":[[2013,7,2]],"date-time":"2013-07-02T10:32:17Z","timestamp":1372761137000},"page":"866-874","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["The Reaction and Materials Chemistry of 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