{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:11:30Z","timestamp":1791349890196,"version":"4.3.1"},"reference-count":42,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2015,9,11]],"date-time":"2015-09-11T00:00:00Z","timestamp":1441929600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001824","name":"Czech Science Foundation","doi-asserted-by":"crossref","award":["13-15576S"],"award-info":[{"award-number":["13-15576S"]}],"id":[{"id":"10.13039\/501100001824","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Czech Ministry of Education","award":["LO1214"],"award-info":[{"award-number":["LO1214"]}]},{"name":"Czech Ministry of Education","award":["LM2011028"],"award-info":[{"award-number":["LM2011028"]}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2015,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Bambus[6]urils are a class of neutral anion receptors with outstanding binding properties in various solvents. The host\u2013guest associations of bambusurils in aqueous environments have been investigated in detail, but their behavior in nonpolar solvents has not yet been reported. This paper presents isothermal calorimetry and <jats:sup>1<\/jats:sup>H\u2005NMR data on the binding of dodecabenzylbambus[6]uril (Bn<jats:sub>12<\/jats:sub>BU[6]) to seventeen anions in chloroform. Under these conditions, anion inclusion in the macrocycle appears to be enthalpy\u2010driven, yielding complexes with stability constants of up to 10<jats:sup>10<\/jats:sup>\u2009<jats:sc>m<\/jats:sc><jats:sup>\u22121<\/jats:sup>. Perchlorate was optimally sized for inclusion in Bn<jats:sub>12<\/jats:sub>BU[6], while larger anions exhibited significantly lower affinity for the macrocycle. In addition, complexes of bambusuril and anions can be differentiated by NMR analysis based on the unique chemical shifts of characteristic peaks in their spectra. This finding was used to perform quantitative and qualitative analysis of multiple anion mixtures.<\/jats:p>","DOI":"10.1002\/cplu.201500345","type":"journal-article","created":{"date-parts":[[2015,8,25]],"date-time":"2015-08-25T05:43:19Z","timestamp":1440481399000},"page":"1601-1606","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":66,"title":["Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform"],"prefix":"10.1002","volume":"80","author":[{"given":"Vaclav","family":"Havel","sequence":"first","affiliation":[{"name":"Department of Chemistry and RECETOX Masaryk University  Kamenice 5 625 00 Brno Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir","family":"Sindelar","sequence":"additional","affiliation":[{"name":"Department of Chemistry and RECETOX Masaryk University  Kamenice 5 625 00 Brno Czech 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