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The nylon fabric, which is metallized with copper, undergoes a spontaneous chemical reaction with TCNAQ dissolved in acetonitrile to form nanorods of CuTCNAQ that are intertwined over the entire surface of the fabric. This creates the necessary micro\u2010 and nanoscale roughness that often allows the Cassie\u2013Baxter state to be obtained with high robustness, thereby achieving a superhydrophobic\/superoleophilic surface without the need for a fluorinated surface. The material is characterized with SEM, FTIR spectroscopy, and X\u2010ray photoelectron spectroscopy, and investigated for its ability to separate oil and water in two modes, namely through filtration and as an absorbent material. It is found that the fabric can separate dichloromethane, olive oil, and crude oil from water, and reduce the water content of the oil during the separation process. The fabric is reusable, highly durable, and tolerant to conditions such as seawater, hydrochloric acid, and extensive time periods on the shelf. Given that CuTCNAQ is a copper\u2010based semiconductor, there may also be the possibility of other uses in areas such as photocatalysis and antibacterial applications.<\/jats:p>","DOI":"10.1002\/cplu.201600021","type":"journal-article","created":{"date-parts":[[2016,2,20]],"date-time":"2016-02-20T12:44:23Z","timestamp":1455972263000},"page":"378-383","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Superhydrophobic Fabrics for Oil\/Water Separation Based on the Metal\u2013Organic Charge\u2010Transfer Complex CuTCNAQ"],"prefix":"10.1002","volume":"81","author":[{"given":"Faegheh","family":"Hoshyargar","sequence":"first","affiliation":[{"name":"School of Chemistry, Physics and Mechanical Engineering Queensland University of Technology (QUT)  GPO Box 2434 Brisbane QLD 4001 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manika","family":"Mahajan","sequence":"additional","affiliation":[{"name":"School of Applied Sciences RMIT University  GPO Box 2476V Melbourne VIC 3001 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"family":"Anuradha","sequence":"additional","affiliation":[{"name":"School of Applied Sciences RMIT University  GPO Box 2476V Melbourne VIC 3001 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sheshanath V.","family":"Bhosale","sequence":"additional","affiliation":[{"name":"School of Applied Sciences RMIT University  GPO Box 2476V Melbourne VIC 3001 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Louis","family":"Kyratzis","sequence":"additional","affiliation":[{"name":"CSIRO Materials Science and Engineering  P. 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