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The strategy is based on noncovalent \u03c0\u2013\u03c0 interactions between multiwalled carbon nanotubes (MWCNTs) and the cationic acetylammonium pyrene moiety (Pyr<jats:sup>+<\/jats:sup>) covalently attached to a NHC IrCp*Cl<jats:sub>2<\/jats:sub> catalytically active center (NHC=N\u2010heterocyclic carbene, Cp*=C<jats:sub>5<\/jats:sub>Me<jats:sub>5<\/jats:sub>). The dispersive properties of the Pyr<jats:sup>+<\/jats:sup> moiety in compound\u2005<jats:bold>3<\/jats:bold> leads to the formation of stable MWCNT dispersions in aqueous solutions. In addition, the MWCNT\/<jats:bold>3<\/jats:bold> assembly shows activity in the Ce<jats:sup>4+<\/jats:sup>\u2010driven oxidation of H<jats:sub>2<\/jats:sub>O. FTO\/MWCNT\/<jats:bold>3<\/jats:bold> anodes show increased current densities when used as a working electrode for the electrocatalytic oxidation of H<jats:sub>2<\/jats:sub>O. At higher anodic polarizations initially high current densities were achieved; however, these currents prove to be non\u2010sustained due to delamination and degradation of the catalytically active surface. The immobilization strategy is limited to applications below 1.4\u2005V vs normal hydrogen electrode (NHE) as oxidation of the pyrene backbone is evident at higher potentials.<\/jats:p>","DOI":"10.1002\/cplu.201600235","type":"journal-article","created":{"date-parts":[[2016,6,7]],"date-time":"2016-06-07T08:09:35Z","timestamp":1465286975000},"page":"1098-1106","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Anode Preparation Strategies for the Electrocatalytic Oxidation of Water Based on Strong Interactions between Multiwalled Carbon Nanotubes and Cationic Acetylammonium Pyrene Moieties in Aqueous Solutions"],"prefix":"10.1002","volume":"81","author":[{"given":"Jacobus M.","family":"Koelewijn","sequence":"first","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"Lutz","sequence":"additional","affiliation":[{"name":"Crystal and Structural Chemistry Bijvoet Center for Biomolecular Research Utrecht University  Padualaan 8 3584 CH Utrecht The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Remko J.","family":"Detz","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5024-508X","authenticated-orcid":false,"given":"Joost N. 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