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The BChl\u2010<jats:italic>c<\/jats:italic> gel was evaluated by several spectroscopic measurements: the electronic absorption spectrum exhibited a far\u2010red shift of the Qy\u2010absorption from 660 to 748\u2005nm and the FTIR spectrum showed a shorter frequency shift of the 13\u2010C=O stretching from 1683 to 1643\u2005cm<jats:sup>\u22121<\/jats:sup> compared to the shifts of the corresponding monomer solution in tetrahydrofuran. These observations strongly indicate that the gelating BChl\u2010<jats:italic>c<\/jats:italic> molecules form self\u2010aggregates that are reminiscent of light\u2010harvesting chlorosomes of green photosynthetic bacteria. The present supramolecular organogel prepared from natural chlorophylls is promising for the creation of an intelligent soft material involving artificial photosynthesis.<\/jats:p>","DOI":"10.1002\/cplu.201600494","type":"journal-article","created":{"date-parts":[[2016,10,28]],"date-time":"2016-10-28T11:43:18Z","timestamp":1477654998000},"page":"595-597","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Supramolecular Organogelation of Bacteriochlorophyll\u2010<i>c<\/i> Possessing an Isobutyl Substituent at the 8\u2010Position in Carbon Tetrachloride"],"prefix":"10.1002","volume":"82","author":[{"given":"Tadashi","family":"Mizoguchi","sequence":"first","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Noji-higashi 1-1-1, Kusatsu Shiga 525-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuke","family":"Kinoshita","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Noji-higashi 1-1-1, Kusatsu Shiga 525-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiro","family":"Harada","sequence":"additional","affiliation":[{"name":"Department of Medical Biochemistry Kurume University School of Medicine  Kurume Fukuoka 830-0011 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hitoshi","family":"Tamiaki","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Noji-higashi 1-1-1, Kusatsu Shiga 525-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,11,10]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-017-2087-8_6"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1998.tb05166.x"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/b137480"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2005.06.001"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(95)01188-9"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1007\/1-4020-4516-6_1"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1111\/mmi.13208"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1014955614757"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0006-3495(03)74678-5"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp071559p"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep00671"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1017\/S0033583506004434"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527623464.ch12"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424614500710"},{"key":"e_1_2_2_20_1","unstructured":"\u00a0"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199607721"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961080712"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1522-2675(19990609)82:6<797::AID-HLCA797>3.0.CO;2-9"},{"key":"e_1_2_2_23_1","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp992338p"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2013.06.012"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b00781"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1562\/0031-8655(2000)0710596STATAF2.0.CO2"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0013356"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/b416360e"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0060026"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11120-014-9977-8"},{"key":"e_1_2_2_34_1","unstructured":"\u00a0"},{"key":"e_1_2_2_35_2","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1007\/BF00035681","volume":"30","author":"Olson J. 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