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Among the cleavage techniques, liquid\u2010phase exfoliation is now on the rise because it is scalable and leads to easy\u2010to\u2010manipulate colloids. However, all appropriate exfoliating solvents exhibit strong polarity, which greatly restricts the scope of feasible functionalization or processing of the resulting flakes. Here, this scope is extended: nanosheets exfoliated in a polar medium are demonstrated to properly disperse in a nonpolar solvent. To that purpose, suspensions of molybdenum disulfide flakes were prepared in isopropanol\/water and a phase transfer of the nanosheets to chloroform was developed by flocculation and redispersion\/centrifugation sequences, without any assisting surfactant. The colloidal stability of the nanosheets in chloroform was found to be governed by their lateral dimensions and, although lower than in polar media, proved to be high enough to open the way to subsequent functionalization or processing of the flakes in nonpolar media.<\/jats:p>","DOI":"10.1002\/cplu.201700038","type":"journal-article","created":{"date-parts":[[2017,4,5]],"date-time":"2017-04-05T15:32:00Z","timestamp":1491406320000},"page":"732-741","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Surfactant\u2010Free Polar\u2010to\u2010Nonpolar Phase Transfer of Exfoliated MoS<sub>2<\/sub> Two\u2010Dimensional Colloids"],"prefix":"10.1002","volume":"82","author":[{"given":"Emerson","family":"Giovanelli","sequence":"first","affiliation":[{"name":"IMDEA Nanociencia Ciudad Universitaria de Cantoblanco  Calle Faraday 9 28049 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andres","family":"Castellanos\u2010Gomez","sequence":"additional","affiliation":[{"name":"IMDEA Nanociencia Ciudad Universitaria de Cantoblanco  Calle Faraday 9 28049 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8739-2777","authenticated-orcid":false,"given":"Emilio M.","family":"P\u00e9rez","sequence":"additional","affiliation":[{"name":"IMDEA Nanociencia Ciudad Universitaria de Cantoblanco  Calle Faraday 9 28049 Madrid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,4,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1102896"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.105.136805"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500303m"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201102584"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm5044864"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11458"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1194975"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2008.215"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3213"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b01842"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b07228"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105364"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105364"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA00212A"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5576"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9563"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b00910"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14409"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201502303"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.3390\/ijms160510704"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505345"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2015.08.019"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201510219"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201510219"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201604176"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b03335"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9294"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08096"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0154522"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.38051"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc00425f"},{"volume-title":"Handbook of Organic Solvent Properties","year":"1996","author":"Smallwood I. 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