{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:37:54Z","timestamp":1786977474501,"version":"build-2736575974"},"reference-count":60,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2018,11,8]],"date-time":"2018-11-08T00:00:00Z","timestamp":1541635200000},"content-version":"vor","delay-in-days":7,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004350","name":"Studienstiftung des deutschen Volkes","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100004350","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2018,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A carboranyl\u2010based\n                    <jats:italic>meso<\/jats:italic>\n                    \u20101,2,5\u2010selenadiphospholane diselenide was synthesised starting from a strained carborane\u2010substituted 1,2\u2010diphosphetane and subsequently reduced to an unprecedented carboranyl\u2010based\n                    <jats:italic>meso<\/jats:italic>\n                    \u20101,2,5\u2010selenadiphospholane. The electronic structure and the bonding situation for both compounds were investigated by density functional theory (DFT), Natural Bond Orbital (NBO) analyses, Fractional Occupation Density (FOD) analysis, Complete Active Space Self Consistent Field (CASSCF) calculations and time\u2010dependent DFT (TDDFT) calculations. Ring\u2010opening reactions of\n                    <jats:italic>meso<\/jats:italic>\n                    \u20101,2,5\u2010selenadiphospholane with nucleophiles and electrophiles are reported together with calculated reaction mechanisms (DFT level). Isolated compounds were characterised by NMR and IR spectroscopy, high\u2010resolution mass spectrometry, elemental analysis and single\u2010crystal X\u2010ray diffraction.\n                  <\/jats:p>","DOI":"10.1002\/cplu.201800391","type":"journal-article","created":{"date-parts":[[2018,10,11]],"date-time":"2018-10-11T11:05:53Z","timestamp":1539255953000},"page":"1057-1064","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Exploiting the Ring Strain of Diphosphetanes: A Synthetic and Computational Approach towards 1,2,5\u2010Selenadiphospholanes"],"prefix":"10.1002","volume":"83","author":[{"given":"Peter","family":"Coburger","sequence":"first","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard","family":"Aures","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paulina","family":"Schulz","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4267-0603","authenticated-orcid":false,"given":"Evamarie","family":"Hey\u2010Hawkins","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,11,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"crossref","unstructured":"P.\u2005C.\u2005J. 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