{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,28]],"date-time":"2026-01-28T20:19:50Z","timestamp":1769631590397,"version":"3.49.0"},"reference-count":95,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T00:00:00Z","timestamp":1549497600000},"content-version":"vor","delay-in-days":6,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Nature Science Foundation of china","award":["51569008"],"award-info":[{"award-number":["51569008"]}]},{"name":"Nature Science Foundation of china","award":["21861014"],"award-info":[{"award-number":["21861014"]}]},{"name":"Program of the Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi","award":["GXYSXTZX2017-II-3"],"award-info":[{"award-number":["GXYSXTZX2017-II-3"]}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2019,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Cadmium\u2010based coordination polymers, namely, <jats:bold>{<\/jats:bold>[Cd(HL)(L)]\u2009\u22c5\u2009HN(Et)<jats:sub>3<\/jats:sub>}<jats:sub>n<\/jats:sub> (<jats:bold>1<\/jats:bold>), [Cd<jats:sub>2<\/jats:sub>(L)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>5<\/jats:sub>]<jats:sub>n<\/jats:sub> (<jats:bold>2<\/jats:bold>), [Cd(L)(phen)]<jats:sub>n<\/jats:sub> (<jats:bold>3<\/jats:bold>), [Cd(L)(2,2\u2032\u2010bpy)]<jats:sub>n<\/jats:sub> (<jats:bold>4<\/jats:bold>), [Cd(L)(4,4\u2032\u2010bpy)]<jats:sub>n<\/jats:sub> (<jats:bold>5<\/jats:bold>), [Cd(L)(bpp)]<jats:sub>n<\/jats:sub> (<jats:bold>6<\/jats:bold>), [Cd(L)(dpa)]<jats:sub>n<\/jats:sub> (<jats:bold>7<\/jats:bold>), {[Cd(L)(dpa)]\u2009\u22c5\u2009H<jats:sub>2<\/jats:sub>O}<jats:sub>n<\/jats:sub> (<jats:bold>8<\/jats:bold>) (H<jats:sub>2<\/jats:sub>L=4,4\u2032\u2010((p\u2010tolylazanediyl)bis(methylene))dibenzoic acid, phen=1,10\u2010phenanthroline, 2,2\u2032\u2010bpy=2,2\u2032\u2010bipyridine, 4,4\u2032\u2010bpy=4,4\u2032\u2010bipyridine, bpp=1,3\u2010bis(4\u2010pyridyl)propane, dpa=bis(4\u2010pyridyl)amine) have been synthesized in hydro\/solvothermal reactions. <jats:bold>1<\/jats:bold> is a 4\u2010connect 3D network with an eightfold interpenetrating diamond topology. The 1D ladder chain structure of <jats:bold>2<\/jats:bold> was composed of the dinuclear [Cd<jats:sub>2<\/jats:sub>(CO<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>] subunit bridged with two L<jats:sup>2\u2212<\/jats:sup> ligands. <jats:bold>3<\/jats:bold> shows a 1D double\u2010chain with a channel formed by edging out the coordination water with the rigid co\u2010ligand phen. Polymer <jats:bold>4<\/jats:bold> displays a 2D lamellar structure based on superseding the coordination water molecules by the rigid chelating auxiliary ligands 2,2\u2032\u2010bpy. By substituting the small molecules with a rigid bridging ligand 4,4\u2032\u2010bpy, a 2D undulating structure of <jats:bold>5<\/jats:bold> was built. Compounds <jats:bold>6<\/jats:bold> and <jats:bold>7<\/jats:bold> exhibit a 2D layer structure with a 4\u2010connect (4<jats:sup>4<\/jats:sup>\u2009\u22c5\u20096<jats:sup>2<\/jats:sup>) <jats:bold>sql<\/jats:bold>\u2010net. Compound <jats:bold>8<\/jats:bold> presents a 3D architecture with a sixfold interpenetrating diamond topology. Through our construction strategy, versatile structures from 1D\u20133D have been rationally designed by controlling the process condition and rigid\/flexible of N\u2010donor spacers. Additionally, the photoluminescence, charge transfer, and electrochemical luminescence (ECL) properties of <jats:bold>1\u20138<\/jats:bold> have been demonstrated.<\/jats:p>","DOI":"10.1002\/cplu.201800569","type":"journal-article","created":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T17:11:59Z","timestamp":1549559519000},"page":"190-202","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":30,"title":["Cadmium\u2010Based Coordination Polymers from 1D to 3D: Synthesis, Structures, and Photoluminescent and Electrochemiluminescent Properties"],"prefix":"10.1002","volume":"84","author":[{"given":"Zhonghang","family":"Chen","sequence":"first","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuhua","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shaomei","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Quanchun","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu","family":"Xiao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kai","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials) Guilin University of Technology  No. 12, Jian gan RD, Guilin Guangxi 541004 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,2,7]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00940E"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00095"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc47286h"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature17430"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02923"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00091"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00033B"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00724D"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00930A"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.05.007"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2015.04.009"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2014.02.012"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b01320"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201605637"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC05372F"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.optmat.2017.02.015"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b00428"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg5006133"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09596K"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja508962m"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4tc00329b"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2018.02.012"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic101935f"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm503767r"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg200142f"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg300612k"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00522"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067208"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm304037x"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT01282E"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic402514n"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mencom.2016.09.029"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CE00710K"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CE26521D"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2013.12.002"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00592"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2015.03.018"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2015.07.011"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.5b00001"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08418K"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02540"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4766"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01613"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn5027092"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201501310"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2015.27"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA05018A"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2012.02.025"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2013.06.013"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01222"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201600423"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.02.049"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.09.002"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b05041"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2016.10.003"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2017.10.040"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2014.12.031"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac9914519"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500909"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4ay00805g"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2016.09.067"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja043721x"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt00015b"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssensors.5b00189"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/la901661v"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT04059D"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.01.049"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2013.03.018"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ce25605c"},{"key":"e_1_2_7_70_1","first-page":"71","author":"Spek A. L.","journal-title":"Acta Crystallogr."},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0348244"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg049587"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/B508332J"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg2015644"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60232j"},{"key":"e_1_2_7_76_1","first-page":"2185","author":"Andrea B.","year":"2008","journal-title":"Chem. Commun."},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE01706A"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00571"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA04989J"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc03495a"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc11628b"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2011.09.012"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc11529d"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2015.12.080"},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020373d"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_7_87_1","first-page":"71","author":"Sheldrick G. M.","journal-title":"Acta Crystallogr."},{"key":"e_1_2_7_88_1","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone B. Mennucci G.\u2005A. Petersson H. Nakatsuji M. Caricato X. Li H.\u2005P. Hratchian A.\u2005F. Izmaylov J. Bloino G. Zheng J.\u2005L. Sonnenberg M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven J.\u2005J.\u2005A. Montgomery J.\u2005E. Peralta F. Ogliaro M. Bearpark J.\u2005J. Heyd E. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov R. Kobayashi J. Normand K. Raghavachari A. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi N. Rega J.\u2005M. Millam M. Klene J.\u2005E. Knox J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma V.\u2005G. Zakrzewski G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg S. Dapprich A.\u2005D. Daniels O. Farkas J.\u2005B. Foresman J.\u2005V. Ortiz J. Cioslowski D.\u2005J. Fox Gaussian 09 revision A.02; Gaussian Inc.: Wallingford CT 2009."},{"key":"e_1_2_7_89_1","unstructured":"\u00a0"},{"key":"e_1_2_7_90_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(89)87234-3"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.448799"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2013.07.012"},{"key":"e_1_2_7_95_1","unstructured":"GaussView Version 5 R. Dennington T. Keith J. Millam Semichem Inc.: Shawnee Mission KS 2009."}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcplu.201800569","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.201800569","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:06:30Z","timestamp":1760403990000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.201800569"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,2]]},"references-count":95,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2019,2]]}},"alternative-id":["10.1002\/cplu.201800569"],"URL":"https:\/\/doi.org\/10.1002\/cplu.201800569","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"value":"2192-6506","type":"print"},{"value":"2192-6506","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,2]]},"assertion":[{"value":"2018-11-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-02-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}