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As ligands, six different <jats:italic>N<\/jats:italic>\u2010substituted tetrazoles were applied, leading to the formation of high\u2010nitrogen containing complexes. The obtained compounds were characterized in detail by single crystal as well as powder XRD, IR, EA, DTA, and TGA. In addition, the sensitivities towards impact and friction were determined with BAM standard techniques as well as the sensitivity towards electrostatic discharges. All compounds show moderate sensitivities (<jats:italic>IS<\/jats:italic>&gt;6, <jats:italic>FS<\/jats:italic>&gt;80\u2005N) and energetic properties but differ in their polymeric structures forming polymeric chains or layers up to 3D networks.<\/jats:p>","DOI":"10.1002\/cplu.202000156","type":"journal-article","created":{"date-parts":[[2020,3,23]],"date-time":"2020-03-23T06:41:22Z","timestamp":1584945682000},"page":"769-775","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Copper(II) Dicyanamide Complexes with <i>N<\/i>\u2010Substituted Tetrazole Ligands \u2013 Energetic Coordination Polymers with Moderate Sensitivities"],"prefix":"10.1002","volume":"85","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5494-9903","authenticated-orcid":false,"given":"Maximilian H. 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