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Large yellow crystals (ranging from mm to cm size) of ten different salen derivatives were obtained and investigated. Among them, (bis(2\u2010hydroxyacetophenone)ethylenediimine)\n                    <jats:bold>2<\/jats:bold>\n                    , which was recrystallized from dichloromethane, tetrahydrofuran or chloroform, exhibited plastic deformation behaviour when mechanical force was applied to the (001) face. In contrast, when\n                    <jats:bold>2<\/jats:bold>\n                    was recrystallized from benzene, brittle crystals were obtained. Face indexing confirmed that different crystal faces were obtained by depending on the solvent employed for recrystallization, which leads to either flexible (plastic) or brittle crystals. Photoluminescence with a band maximum at 510\u2005nm and thermochromism related to tautomerism between OH and NH forms were also investigated, and indicate that\n                    <jats:bold>2<\/jats:bold>\n                    is a flexible organic single\u2010crystal material with multifunctional properties.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202000362","type":"journal-article","created":{"date-parts":[[2020,5,23]],"date-time":"2020-05-23T01:49:09Z","timestamp":1590198549000},"page":"1692-1696","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Solvent\u2010Dependent Bending Ability of Salen\u2010Derived Organic Crystals"],"prefix":"10.1002","volume":"85","author":[{"given":"Sotaro","family":"Kusumoto","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science and Technology Kumamoto University  2-39-1 Kurokami, Chuo-ku Kumamoto 860-8555 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