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A comparison of the catalytic properties of as\u2010synthesized and reduced (denoted \u201cr\u201d) catalysts as well as Pd\u2212Cu alloy and monometallic palladium NPs showed a considerable enhancement of the catalytic performance of Pd\u2212Cu\/HPS\u2010r compared to other catalysts studied, resulting in about 100\u2009% FF conversion, 95.2\u2009% selectivity for FA and a TOF of 1209\u2005h<jats:sup>\u22121<\/jats:sup>. This was attributed to the enrichment of the NP surface with copper atoms, disrupting the furan ring adsorption, and to the presence of both zerovalent and cationic palladium and copper species, resulting in optimal hydrogen and FF adsorption. These factors along with exceptional stability of the catalyst in ten consecutive catalytic cycles make it highly promising in practical applications.<\/jats:p>","DOI":"10.1002\/cplu.202000383","type":"journal-article","created":{"date-parts":[[2020,6,29]],"date-time":"2020-06-29T09:57:20Z","timestamp":1593424640000},"page":"1697-1703","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Selective Hydrogenation of Biomass\u2010Derived Furfural: Enhanced Catalytic Performance of Pd\u2212Cu Alloy Nanoparticles in Porous Polymer"],"prefix":"10.1002","volume":"85","author":[{"given":"Ksenia E.","family":"Salnikova","sequence":"first","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"},{"name":"Regional technological centre Tver State University  Zhelyabova str., 33 170100 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yurii V.","family":"Larichev","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis  5 Academician Lavrentiev Avenue 630090 Novosibirsk Russia"},{"name":"Novosibirsk State University  2 Pirogov Street 630090 Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Esther M.","family":"Sulman","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexey V.","family":"Bykov","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander I.","family":"Sidorov","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Galina N.","family":"Demidenko","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mikhail G.","family":"Sulman","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Chemistry Tver State Technical University  A.Nikitin str., 22 170026 Tver Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0438-8132","authenticated-orcid":false,"given":"Lyudmila M.","family":"Bronstein","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. 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