{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T15:52:31Z","timestamp":1787241151446,"version":"build-2736575974"},"reference-count":72,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2020,12,2]],"date-time":"2020-12-02T00:00:00Z","timestamp":1606867200000},"content-version":"vor","delay-in-days":1,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["DTP Scheme"],"award-info":[{"award-number":["DTP Scheme"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2020,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>This Minireview summarises and critically evaluates recent advances in the utilisation of discrete first\u2010row transition\u2010metal (TM) complexes as photosensitisers. Whilst many compounds absorb light, TM complexes are generally more desirable for photochemical applications, as they usually exhibit strong absorption of visible light, making them ideally suited to exploiting the sun as a freely available light source. Due to their outstanding activities, precious metals, such as iridium and ruthenium, are currently still at the forefront of photochemistry research. However, they also bear disadvantages with respect to abundance, cost and toxicity. Therefore, it is desirable to move to more abundant and less expensive systems that retain good photosensitising abilities. This Minireview will focus on first\u2010row transition\u2010metals, specifically titanium, copper, iron, and zinc, which have become the focus of increased attention over recent years as potential replacements for noble metals as photosensitisers. Their structure \u2013 activity relationships are explored and challenges in designing the ligands and complexes are discussed.<\/jats:p>","DOI":"10.1002\/cplu.202000610","type":"journal-article","created":{"date-parts":[[2020,12,2]],"date-time":"2020-12-02T17:05:52Z","timestamp":1606928752000},"page":"2611-2618","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Application of Discrete First\u2010Row Transition\u2010Metal Complexes as Photosensitisers"],"prefix":"10.1002","volume":"85","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5727-6820","authenticated-orcid":false,"given":"Kira","family":"Behm","sequence":"first","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7563-5655","authenticated-orcid":false,"given":"Ruaraidh 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