{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T17:39:05Z","timestamp":1787506745391,"version":"build-2736575974"},"reference-count":32,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2022,11,24]],"date-time":"2022-11-24T00:00:00Z","timestamp":1669248000000},"content-version":"vor","delay-in-days":23,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004482","name":"Kuwait University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004482","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2022,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Tuning the amphiphilicity of (aza)phthalocyanine hydrophobic cores by introducing multiple polyethylene glycol (PEG) moieties with controlled orientations of their (non)peripheral positions is an innovative approach to fabricating water\u2010soluble macrocyclic materials. Although many water\u2010soluble PEGylated macrocycles have been produced in this way, the ability to generate substances with PEG tails oriented outward from the macrocyclic plane in order to obtain non\u2010aggregated, water soluble forms remains a challenge. In this study, we resolved this issue by developing a methods for the synthesis of four new dual directional PEG containing Zn(II)\/Mg(II) amphiphiles (\n                    <jats:bold>ZnPc\u2212PEG<\/jats:bold>\n                    ,\n                    <jats:bold>MgPc\u2212PEG<\/jats:bold>\n                    ,\n                    <jats:bold>ZnAzaPc\u2212PEG<\/jats:bold>\n                    and\n                    <jats:bold>MgAzaPc\u2212PEG<\/jats:bold>\n                    ). In addition, the non\u2010aggregating behaviour, and photophysical and photochemical properties of these PEG\u2010complexes were elucidated.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202200275","type":"journal-article","created":{"date-parts":[[2022,11,3]],"date-time":"2022-11-03T07:18:47Z","timestamp":1667459927000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synthesis, Characterization, and Physicochemical Studies Of Orientation\u2010Controlled Multi\u2010Arm PEG Zn(II)\/Mg(II) (Aza)Phthalocyanines"],"prefix":"10.1002","volume":"87","author":[{"given":"A.","family":"Husain","sequence":"first","affiliation":[{"name":"Department of Chemistry Kuwait University P.O. Box 5969  Safat 13060 Kuwait"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A.","family":"Ganesan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Kuwait University P.O. 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