{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:05:36Z","timestamp":1760403936282,"version":"build-2065373602"},"reference-count":38,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T00:00:00Z","timestamp":1665619200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2023,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A co\u2010crystalline adduct consisting of a phosphinine selenide and an organohalide was obtained by slow evaporation of the solvent from a mixture of 2,6\u2010bis(trimethylsilyl)phosphinine selenide and 1,4\u2010diiodotetrafluorobenzene (1,4\u2010TFDIB). The crystallographic characterization of the product shows \u03c0\u2010\u03c0 stacking, F\u22c5\u22c5\u22c5H hydrogen bonding between 1,4\u2010TFDIB and the phosphinine selenide, as well as F\u22c5\u22c5\u22c5F interactions between 1,4\u2010TFDIB molecules. Moreover, the phosphorus heterocycle could be crystallized with diiodine to form a 1\u2009:\u20091 adduct. The <jats:italic>d<\/jats:italic><jats:sub>(I\u2212I)<\/jats:sub> distance in this compound is 2.8475(3)\u2005\u00c5, which is shorter than the corresponding one in triphenylphosphine selenide diiodide, reflecting the weaker net\u2010donor power of the phosphinine selenide towards diiodine. The phosphinine selenide could also be used as a selenium transfer reagent to generate KSeCN from KCN.<\/jats:p>","DOI":"10.1002\/cplu.202200284","type":"journal-article","created":{"date-parts":[[2022,9,30]],"date-time":"2022-09-30T03:30:03Z","timestamp":1664508603000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Phosphinine Selenide: Noncovalent Interactions with Organoiodines and Elemental Iodine, and Reactivity towards Potassium Cyanide"],"prefix":"10.1002","volume":"88","author":[{"given":"Jinxiong","family":"Lin","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstr. 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nathan T.","family":"Coles","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstr. 34\/36 14195 Berlin Germany"},{"name":"School of Chemistry University of Nottingham  University Park Campus NG7\u20052RD Nottingham UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manuela","family":"Weber","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstr. 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4700-0502","authenticated-orcid":false,"given":"Christian","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstr. 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,10,13]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"For recent examples see"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC04277G"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06997"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03159"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00113"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704753"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.2174\/138527206778521231"},{"key":"e_1_2_8_8_1","unstructured":"\u00a0"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b101002f"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja209246z"},{"volume-title":"Phosphorus (III) ligands in homogeneous catalysis: design and synthesis","year":"2012","author":"Gillespie J. A.","key":"e_1_2_8_11_1"},{"key":"e_1_2_8_12_1","unstructured":"\u00a0"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg201348u"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202100042"},{"key":"e_1_2_8_15_1","unstructured":"\u00a0"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00527"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X63000979"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.0c00823"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07957-6"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CE02118J"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.5b01663"},{"key":"e_1_2_8_22_1","unstructured":"\u00a0"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b00544"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.8b00918"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50004a012"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/a706180c"},{"key":"e_1_2_8_27_1","unstructured":"\u00a0"},{"key":"e_1_2_8_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0006-3495(04)74279-4"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/la901989j"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.5b00783"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202102390"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/b702851b"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768185002129"},{"key":"e_1_2_8_34_1","unstructured":"A. Shlyaykher M. Ehmann A.\u2005J. Karttunen F. Tambornino CCDC 2080510: Experimental Crystal Structure Determination 2021 DOI: 10.5517\/ccdc.csd.cc27ty78."},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1080\/08893110802547240"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202200284","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cplu.202200284","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202200284","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T22:11:13Z","timestamp":1760393473000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.202200284"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10,13]]},"references-count":38,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2023,4]]}},"alternative-id":["10.1002\/cplu.202200284"],"URL":"https:\/\/doi.org\/10.1002\/cplu.202200284","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"type":"print","value":"2192-6506"},{"type":"electronic","value":"2192-6506"}],"subject":[],"published":{"date-parts":[[2022,10,13]]},"assertion":[{"value":"2022-08-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-10-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202200284"}}