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Higher contents in Cu\u2212Salphen yielded larger and more homogeneous polymer sizes. Polymer size together with glass transitions, heat capacity, thermal degradation, guest\u2010saturation degrees and host\u2010guest species distribution profiles from spectrophotometric titrations explained growths of up to 630\u2010fold in <jats:italic>K<\/jats:italic><jats:sub>11<\/jats:sub> and 180000\u2010fold in <jats:italic>K<\/jats:italic><jats:sub>12<\/jats:sub> for the host's binding site attributable to a solvophobic protection from the macromolecular structure. Spectrofluorimetry revealed blue\u2010shifted\u00d713\u201316 larger luminescence for Cu\u2212Salphen in the polymers (\u03bb<jats:sub>em<\/jats:sub>=488\u2013498\u2005nm) than that of the non\u2010polymerized counterpart (\u03bb<jats:sub>em<\/jats:sub>=510\u2013543\u2005nm) and \u201cturn\u2010on\u201d blue\u2010shifted enhanced fluorescence upon guest association. We propose a cooperative incorporation of the guests occurring from the outer medium toward internally protected binding site pockets in the random coil polymer conformations.<\/jats:p>","DOI":"10.1002\/cplu.202200310","type":"journal-article","created":{"date-parts":[[2022,9,14]],"date-time":"2022-09-14T13:54:09Z","timestamp":1663163649000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Enhanced Host\u2010Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anions"],"prefix":"10.1002","volume":"88","author":[{"given":"Paulina","family":"Hern\u00e1ndez\u2010Pacheco","sequence":"first","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gustavo A.","family":"Zelada\u2010Guill\u00e9n","sequence":"additional","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Margarita","family":"Romero\u2010\u00c1vila","sequence":"additional","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roberto Carlos","family":"Ca\u00f1as\u2010Alonso","sequence":"additional","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcos","family":"Flores\u2010\u00c1lamo","sequence":"additional","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martha V.","family":"Esc\u00e1rcega\u2010Bobadilla","sequence":"additional","affiliation":[{"name":"School of Chemistry National Autonomous University of Mexico (UNAM)  Circuito Escolar s\/n, Ciudad Universitaria Mexico City 04510 Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,9,29]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00405"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500116d"},{"key":"e_1_2_8_4_2","doi-asserted-by":"crossref","unstructured":"F. 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