{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T00:09:10Z","timestamp":1760486950170,"version":"build-2065373602"},"reference-count":59,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2023,2,28]],"date-time":"2023-02-28T00:00:00Z","timestamp":1677542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["DI 2054\/1-1"],"award-info":[{"award-number":["DI 2054\/1-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2023,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>1,4\u2010Diphosphabarrelenes are bicyclic diphosphines relevant, for example, for the generation of polymetallic coordination compounds. However, current synthetic protocols either suffer from low yields or require multiple reaction steps. Herein, we report the one\u2010step synthesis of pyrrole\u2010based 1,4\u2010diphosphabarrelenes that are obtained in very good yields from the reaction of 1,2,5\u2010trimethylpyrrole with 1,2\u2010bis(dichlorophosphino)ethane or 1,2\u2010bis(dichlorophosphino)benzene. The new caged diphosphines are strong donor ligands and act as bridging ligand in nickel(0), rhodium(I), iridium(I) and copper(I) coordination compounds.<\/jats:p>","DOI":"10.1002\/cplu.202200458","type":"journal-article","created":{"date-parts":[[2023,2,2]],"date-time":"2023-02-02T04:49:44Z","timestamp":1675313384000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Facile One\u2010Step Access to Pyrrole\u2010Based 1,4\u2010Diphosphabarrelenes"],"prefix":"10.1002","volume":"88","author":[{"given":"Janina A.","family":"Werra","sequence":"first","affiliation":[{"name":"Institute of General Inorganic and Theoretical Chemistry Leopold-Franzens-Universit\u00e4t Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"},{"name":"Institute of Inorganic and Analytical Chemistry Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster  Corrensstrasse 28\/30 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8774-9051","authenticated-orcid":false,"given":"Klaus","family":"Wurst","sequence":"additional","affiliation":[{"name":"Institute of General Inorganic and Theoretical Chemistry Leopold-Franzens-Universit\u00e4t Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2275-552X","authenticated-orcid":false,"given":"Pawel","family":"L\u00f6we","sequence":"additional","affiliation":[{"name":"Institute of Inorganic and Analytical Chemistry Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster  Corrensstrasse 28\/30 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7025-5450","authenticated-orcid":false,"given":"Fabian","family":"Dielmann","sequence":"additional","affiliation":[{"name":"Institute of General Inorganic and Theoretical Chemistry Leopold-Franzens-Universit\u00e4t Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,2,28]]},"reference":[{"doi-asserted-by":"publisher","key":"e_1_2_8_1_1","DOI":"10.1039\/D0QO01194K"},{"doi-asserted-by":"publisher","key":"e_1_2_8_2_1","DOI":"10.1021\/jacs.0c12816"},{"doi-asserted-by":"publisher","key":"e_1_2_8_3_1","DOI":"10.1002\/anie.196807331"},{"unstructured":"\u00a0","key":"e_1_2_8_4_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_5_2","DOI":"10.1039\/b814886d"},{"doi-asserted-by":"publisher","key":"e_1_2_8_6_2","DOI":"10.1021\/om0490278"},{"doi-asserted-by":"publisher","key":"e_1_2_8_7_2","DOI":"10.1055\/s-2006-942425"},{"doi-asserted-by":"publisher","key":"e_1_2_8_8_2","DOI":"10.1002\/chem.201900938"},{"doi-asserted-by":"publisher","key":"e_1_2_8_9_1","DOI":"10.1002\/chem.201903344"},{"unstructured":"\u00a0","key":"e_1_2_8_10_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_11_2","DOI":"10.1039\/b911612e"},{"doi-asserted-by":"publisher","key":"e_1_2_8_12_2","DOI":"10.1002\/chem.200600180"},{"doi-asserted-by":"publisher","key":"e_1_2_8_13_2","DOI":"10.1039\/B315709A"},{"unstructured":"\u00a0","key":"e_1_2_8_14_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_15_2","DOI":"10.1134\/S1070363220070130"},{"doi-asserted-by":"publisher","key":"e_1_2_8_16_2","DOI":"10.1007\/978-90-481-3817-3_6"},{"key":"e_1_2_8_17_2","first-page":"147","volume-title":"Phosphorous Heterocycles I","author":"Floch P.","year":"2009"},{"doi-asserted-by":"publisher","key":"e_1_2_8_18_2","DOI":"10.2174\/138527206775193004"},{"doi-asserted-by":"publisher","key":"e_1_2_8_19_1","DOI":"10.1021\/ja01477a019"},{"unstructured":"\u00a0","key":"e_1_2_8_20_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_21_2","DOI":"10.1021\/ja00736a050"},{"doi-asserted-by":"publisher","key":"e_1_2_8_22_2","DOI":"10.1021\/jo00912a027"},{"doi-asserted-by":"publisher","key":"e_1_2_8_23_1","DOI":"10.1016\/S0022-328X(00)89361-4"},{"doi-asserted-by":"publisher","key":"e_1_2_8_24_1","DOI":"10.1246\/bcsj.82.819"},{"doi-asserted-by":"publisher","key":"e_1_2_8_25_1","DOI":"10.1016\/S0040-4039(00)61405-3"},{"doi-asserted-by":"publisher","key":"e_1_2_8_26_1","DOI":"10.1002\/aoc.590020609"},{"doi-asserted-by":"publisher","key":"e_1_2_8_27_1","DOI":"10.1039\/C7CC09349G"},{"doi-asserted-by":"publisher","key":"e_1_2_8_28_1","DOI":"10.1039\/D0DT02529A"},{"unstructured":"\u00a0","key":"e_1_2_8_29_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_30_2","DOI":"10.1016\/S0040-4039(00)93089-2"},{"doi-asserted-by":"publisher","key":"e_1_2_8_31_2","DOI":"10.1021\/ja00399a079"},{"doi-asserted-by":"publisher","key":"e_1_2_8_32_2","DOI":"10.1021\/jo01311a027"},{"doi-asserted-by":"publisher","key":"e_1_2_8_33_2","DOI":"10.1039\/D1DT01624E"},{"unstructured":"\u00a0","key":"e_1_2_8_34_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_35_2","DOI":"10.1002\/anie.201704070"},{"doi-asserted-by":"publisher","key":"e_1_2_8_35_3","DOI":"10.1002\/ange.201704070"},{"doi-asserted-by":"publisher","key":"e_1_2_8_36_2","DOI":"10.1039\/C8CC08158A"},{"unstructured":"\u00a0","key":"e_1_2_8_37_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_38_2","DOI":"10.1002\/anie.201504993"},{"doi-asserted-by":"publisher","key":"e_1_2_8_38_3","DOI":"10.1002\/ange.201504993"},{"doi-asserted-by":"publisher","key":"e_1_2_8_39_2","DOI":"10.1002\/zaac.202000028"},{"doi-asserted-by":"publisher","key":"e_1_2_8_40_2","DOI":"10.1002\/chem.201904621"},{"doi-asserted-by":"publisher","key":"e_1_2_8_41_2","DOI":"10.1002\/chem.202104021"},{"doi-asserted-by":"publisher","key":"e_1_2_8_42_2","DOI":"10.1002\/chem.201604971"},{"unstructured":"J.\u2005A. Werra K. Wurst L.\u2005F.\u2005B. Wilm P. L\u00f6we M.\u2005B. R\u00f6thel F. Dielmannmanuscript submitted.","key":"e_1_2_8_43_1"},{"unstructured":"\u00a0","key":"e_1_2_8_44_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_45_2","DOI":"10.1016\/j.tetlet.2016.02.069"},{"doi-asserted-by":"publisher","key":"e_1_2_8_46_2","DOI":"10.1002\/hc.1105"},{"unstructured":"Note that following reactions did not give the desired phosphabarrelenes but were unselective according to31P NMR monitoring: The reaction of 1 1-bis(dichlorophosphino)ferrocene with Htmp. The reaction of 1 2-bis(dichlorophosphino)ethane with 1-(2 6-diisopropylphenyl)pyrrole.","key":"e_1_2_8_47_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_48_1","DOI":"10.1021\/cr60307a002"},{"doi-asserted-by":"publisher","key":"e_1_2_8_49_1","DOI":"10.1039\/C6CC02461K"},{"unstructured":"\u00a0","key":"e_1_2_8_50_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_51_2","DOI":"10.1016\/j.ccr.2021.213995"},{"doi-asserted-by":"publisher","key":"e_1_2_8_52_2","DOI":"10.1039\/b200393g"},{"doi-asserted-by":"publisher","key":"e_1_2_8_53_1","DOI":"10.1039\/jr9590002835"},{"unstructured":"\u00a0","key":"e_1_2_8_54_1"},{"doi-asserted-by":"publisher","key":"e_1_2_8_55_2","DOI":"10.1038\/s41570-020-00226-5"},{"doi-asserted-by":"publisher","key":"e_1_2_8_56_2","DOI":"10.1021\/om400613b"},{"doi-asserted-by":"publisher","key":"e_1_2_8_57_2","DOI":"10.1039\/c2cs35129c"}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202200458","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cplu.202200458","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202200458","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:04:14Z","timestamp":1760400254000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.202200458"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,28]]},"references-count":59,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2023,3]]}},"alternative-id":["10.1002\/cplu.202200458"],"URL":"https:\/\/doi.org\/10.1002\/cplu.202200458","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"type":"print","value":"2192-6506"},{"type":"electronic","value":"2192-6506"}],"subject":[],"published":{"date-parts":[[2023,2,28]]},"assertion":[{"value":"2022-12-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-02-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202200458"}}