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Ultrasound (US) was used to improve dispersion and stability of metal nanoparticles, while commercial activated carbon and carbon nanofibers were used as supports. Moreover, various bio\u2010derived molecules were selected as substrates, and aqueous ammonia was used as a cheap and non\u2010toxic reagent. MW combined with heterogeneous Rh catalysts gave a 98.2\u2009% yield in benzylamine at 80\u2009\u00b0C with 10\u2005bar H<jats:sub>2<\/jats:sub> for 1\u2005h; and a 43.3\u2009% yield in phenylethylamine at 80\u2009\u00b0C and 5\u2005bar H<jats:sub>2<\/jats:sub> for 2\u2005h. Carbon nanofibers proved to be a better support for the metal active phase than simple activated carbon, since a limited yield in benzylamine (10.6\u2009%) but a high selectivity for the reductive amination of ketones was obtained. Thus, raspberry ketone was converted to raspberry amine in a 63.0\u2009% yield.<\/jats:p>","DOI":"10.1002\/cplu.202300017","type":"journal-article","created":{"date-parts":[[2023,3,27]],"date-time":"2023-03-27T05:28:03Z","timestamp":1679894883000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Microwave\u2010Assisted Reductive Amination of Aldehydes and Ketones Over Rhodium\u2010Based Heterogeneous Catalysts"],"prefix":"10.1002","volume":"88","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0548-9127","authenticated-orcid":false,"given":"Fabio","family":"Bucciol","sequence":"first","affiliation":[{"name":"Department of Drug Science and Technology and NIS Interdepartmental Centre University of Turin  Via Pietro Giuria 9 10125 Turin Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9602-0310","authenticated-orcid":false,"given":"Emanuela Calcio","family":"Gaudino","sequence":"additional","affiliation":[{"name":"Department of Drug Science and Technology and NIS Interdepartmental Centre University of Turin  Via Pietro Giuria 9 10125 Turin Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8656-6256","authenticated-orcid":false,"given":"Alberto","family":"Villa","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Milan  Via Golgi 19 \u2013 Corpo A 20133 Milan Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Carmen","family":"Valsania","sequence":"additional","affiliation":[{"name":"Department of Chemistry and NIS Interdepartmental Centre University of Turin  Via Pietro Giuria 7 10125 Turin Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7574-7350","authenticated-orcid":false,"given":"Giancarlo","family":"Cravotto","sequence":"additional","affiliation":[{"name":"Department of Drug Science and Technology and NIS Interdepartmental Centre University of Turin  Via Pietro Giuria 9 10125 Turin Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4427-7939","authenticated-orcid":false,"given":"Maela","family":"Manzoli","sequence":"additional","affiliation":[{"name":"Department of Drug Science and Technology and NIS Interdepartmental Centre University of Turin  Via Pietro Giuria 9 10125 Turin Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,3,27]]},"reference":[{"key":"e_1_2_8_1_1","volume-title":"Amino Group Chemistry: From Synthesis to the Life Sciences","author":"Ricci A.","year":"2008"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00437"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60345H"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2009.09.009"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b19865"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/mame.202100568"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601595"},{"key":"e_1_2_8_8_1","volume-title":"Amines: synthesis, properties, and applications","author":"Lawrence S. 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