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The method was further applied to other phosphanes, enabling the first synthesis and complete characterization of 1,2,4\u2010tris(dichlorophosphino)benzene (89\u2009% yield) and 1,2,4,5\u2010tetrakis(dichlorophosphino)benzene (91\u2009% yield), valuable precursors for example for binuclear complexes, coordination polymers, organic wires, or metal\u2013organic frameworks. 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