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This extends the reaction of <jats:bold>1<\/jats:bold> with transition metal carbonyl complexes to further substrates and represents the first examples of insertion of carbonyl compounds into the P\u2212P bond of cyclic oligophosphorus compounds. Complexes <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold> have been characterized by <jats:sup>31<\/jats:sup>P NMR spectroscopy and single crystal X\u2010ray diffraction. Furthermore, the thermal properties of the obtained complexes have been studied by differential scanning calorimetry (DSC) and fast scanning calorimetry (FSC).<\/jats:p>","DOI":"10.1002\/cplu.202300251","type":"journal-article","created":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T02:29:59Z","timestamp":1690856999000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Molybdenum\u2010Mediated Insertion of Ketones into the P\u2212P bond of <i>cyclo<\/i>\u2010(P<sub>5<\/sub>Ph<sub>5<\/sub>) and Formation of Trinuclear Molybdenum Complexes"],"prefix":"10.1002","volume":"88","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3455-7846","authenticated-orcid":false,"given":"Elena","family":"Gorbachuk","sequence":"first","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center Russian Academy of Sciences  Arbuzov str., 8 420088 Kazan Russian 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