{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T02:18:24Z","timestamp":1779070704375,"version":"3.51.4"},"reference-count":38,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2023,11,15]],"date-time":"2023-11-15T00:00:00Z","timestamp":1700006400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001824","name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","doi-asserted-by":"publisher","award":["23-06548S"],"award-info":[{"award-number":["23-06548S"]}],"id":[{"id":"10.13039\/501100001824","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2024,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this study, Ru complexes [(\u03b7<jats:sup>6<\/jats:sup><jats:italic>\u2010p<\/jats:italic>\u2010cymene)RuX(2\u2010{(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH}\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N\u20106\u2010(O))] (<jats:bold>3<\/jats:bold>: X=Cl; <jats:bold>4<\/jats:bold>: X=I) were prepared with <jats:italic>N<\/jats:italic>\u2010bound 2\u2010pyridonato ligand by thermal base\u2010free MeX elimination from ionic <jats:italic>N,N<\/jats:italic>\u2010chelated Ru complexes [(\u03b7<jats:sup>6<\/jats:sup>\u2010<jats:italic>p<\/jats:italic>\u2010cymene)RuX(\u03ba<jats:sup>2<\/jats:sup>\u2010L<jats:sup>1<\/jats:sup>)](X) (<jats:bold>1<\/jats:bold>: X=Cl; <jats:bold>2<\/jats:bold>: X=I; L<jats:sup>1<\/jats:sup>={2\u2010[(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH]\u20106\u2010(OMe)C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N}). The Ru complex <jats:bold>3<\/jats:bold> was used as <jats:italic>O<\/jats:italic>\u2010donor for Lewis (LA) or Br\u00f6nsted acids. The reactions of <jats:bold>3<\/jats:bold> with SnCl<jats:sub>2<\/jats:sub>, Ph<jats:sub>3<\/jats:sub>SnCl, ZnCl<jats:sub>2<\/jats:sub> or HCl provided [(\u03b7<jats:sup>6<\/jats:sup><jats:italic>\u2010p<\/jats:italic>\u2010cymene)Ru(SnCl<jats:sub>3<\/jats:sub>)(2\u2010{(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH}\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N\u20106\u2010(O\u2192SnCl<jats:sub>2<\/jats:sub>)] (<jats:bold>6<\/jats:bold>), [(\u03b7<jats:sup>6<\/jats:sup><jats:italic>\u2010p<\/jats:italic>\u2010cymene)RuCl(2\u2010{(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH}\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N\u20106\u2010(O\u2192SnPh<jats:sub>3<\/jats:sub>Cl)] (<jats:bold>7<\/jats:bold>), and [(\u03b7<jats:sup>6<\/jats:sup><jats:italic>\u2010p<\/jats:italic>\u2010cymene)RuCl(2\u2010{(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH}\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N\u20106\u2010(O\u2192)]<jats:sub>2<\/jats:sub>(\u03bc\u2010ZnCl<jats:sub>2<\/jats:sub>) (<jats:bold>8<\/jats:bold>) and [(\u03b7<jats:sup>6<\/jats:sup>\u2010<jats:italic>p<\/jats:italic>\u2010cymene)RuCl(2\u2010{(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH}\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>N\u20106\u2010(OH)}](Cl) (<jats:bold>9<\/jats:bold>). The easy conversion of the 2\u2010pyridonato ligand in <jats:bold>3<\/jats:bold> to its 2\u2010hydroxypyridine in <jats:bold>9<\/jats:bold> evoked testing of <jats:bold>3<\/jats:bold> and <jats:bold>4<\/jats:bold> as potential catalysts in base\u2010free transfer\u2010hydrogenation of ketones.<\/jats:p>","DOI":"10.1002\/cplu.202300525","type":"journal-article","created":{"date-parts":[[2023,11,2]],"date-time":"2023-11-02T06:14:03Z","timestamp":1698905643000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Ruthenium Complexes with <i>N<\/i>\u2010Bound 2\u2010Pyridonato Ligand as <i>O<\/i>\u2010Donors: A New Synthetic Approach and the Effect on Reactivity"],"prefix":"10.1002","volume":"89","author":[{"given":"Ond\u0159ej","family":"Mo\u017ediak","sequence":"first","affiliation":[{"name":"Department of General and Inorganic Chemistry University of Pardubice  532 10 Pardubice Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ji\u0159\u00ed","family":"Tydlit\u00e1t","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry and Technology University of Pardubice  532 10 Pardubice Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zde\u0148ka","family":"R\u016f\u017ei\u010dkov\u00e1","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry University of Pardubice  532 10 Pardubice Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Libor","family":"Dost\u00e1l","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry University of Pardubice  532 10 Pardubice Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3639-7631","authenticated-orcid":false,"given":"Roman","family":"Jambor","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry University of Pardubice  532 10 Pardubice Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,11,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00932A"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c00287"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC10206A"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(88)87033-5"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.7b00410"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)81229-2"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00039a046"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal10060635"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/b007041f"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01241"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA04696C"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213537"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2016.12.013"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400082t"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.7284"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2019.04.022"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2012.07.058"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800987"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/om5000166"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.5b00710"},{"key":"e_1_2_8_21_1","unstructured":"\u00a0"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja311940s"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00051"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402922"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400273y"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/om5007566"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)98505-X"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matpr.2021.09.232"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b03174"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/om301260j"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY00446H"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9930001191"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5111"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/om9001268"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2011.10.017"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.2c00433"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_38_1","unstructured":"Deposition Numbers2280193(for2\u22c5MeOH) 2280194 (for4) 2280197 (6\u22c5CH2Cl2) 2280198 (7\u22c5C7H8) and 2280199 (8\u22c5MeOH) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202300525","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T16:45:58Z","timestamp":1760373958000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.202300525"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,15]]},"references-count":38,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2024,4]]}},"alternative-id":["10.1002\/cplu.202300525"],"URL":"https:\/\/doi.org\/10.1002\/cplu.202300525","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"value":"2192-6506","type":"print"},{"value":"2192-6506","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,15]]},"assertion":[{"value":"2023-09-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-11-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202300525"}}