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Both Cr and Ga were incorporated by the ion\u2010exchange method. Cr\u2010modified ZSM\u20105 outperforms the Ga\u2010modified ZSM\u20105 and H\u2010ZSM\u20105 catalysts. Cr\u2212H\u2010ZSM\u20105 almost doubled the carbon yield of aromatics compared to H\u2010ZSM\u20105 at an optimum reaction temperature of 450\u2009\u00b0C. Cr\u2212H\u2010ZSM\u20105 produced aromatics with a yield of ~40\u2009%. The effect of dilution in feed on BTX production is also studied. Cr\u2212H\u2010ZSM\u20105 was found to be more active than H\u2010ZSM\u20105. Complete ethanol conversion was obtained with both pure and dilute bioethanol. The Bronsted\u2010Lewis acid (BLA) pair formed after metal incorporation is responsible for dehydrogenation followed by aromatization, leading to increased aromatic production.<\/jats:p>","DOI":"10.1002\/cplu.202300572","type":"journal-article","created":{"date-parts":[[2024,2,10]],"date-time":"2024-02-10T15:39:29Z","timestamp":1707579569000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Cr\u2010 and Ga\u2010Modified ZSM\u20105 Catalyst for the Production of Renewable BTX from Bioethanol"],"prefix":"10.1002","volume":"89","author":[{"given":"Swati","family":"Saini","sequence":"first","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tolulope","family":"Oluokun","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Department of Chemistry University of Ibadan  Ibadan 200005 Nigeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-4049-3454","authenticated-orcid":false,"given":"Bhawna","family":"Sharma","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2984-5344","authenticated-orcid":false,"given":"Akash","family":"Verma","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Vorontsov","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Ariel University  Ariel 407000 Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Panagiotis G.","family":"Smirniotis","sequence":"additional","affiliation":[{"name":"Department of Chemical and Environmental Engineering University of Cincinnati  Cincinnati OH-45221-0012 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Raghuvir","family":"Singh","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nagabhatla","family":"Viswanadham","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6226-0305","authenticated-orcid":false,"given":"Umesh","family":"Kumar","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Petroleum  Dehradun 248005 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,2,27]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"Benzene-toluene-xylene (BTX) market size & share analysis - 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