{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T03:19:49Z","timestamp":1791343189993,"version":"4.3.1"},"reference-count":136,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2024,4,11]],"date-time":"2024-04-11T00:00:00Z","timestamp":1712793600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The first examples of tetrasubstituted conjugated bis\u2010guanidinate (CBG) supported monomeric and thermally stable gallium dihalides [LGaX\n                    <jats:sub>2<\/jats:sub>\n                    ], (X=Cl (\n                    <jats:bold>Ga\u2212Cl<\/jats:bold>\n                    ), I (\n                    <jats:bold>Ga\u2212I<\/jats:bold>\n                    )) and dihydride (\n                    <jats:bold>Ga\u2212H<\/jats:bold>\n                    ) [LGaH\n                    <jats:sub>2<\/jats:sub>\n                    ] (where L={(ArHN)(ArN)\u2212C=N\u2212C=(NAr)(NHAr)}; Ar=2,6\u2010Et\n                    <jats:sub>2<\/jats:sub>\n                    \u2212C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    ) compounds are reported. The reaction of\n                    <jats:italic>in\u2005situ<\/jats:italic>\n                    generated LLi with 1.0\u2005equiv. GaX\n                    <jats:sub>3<\/jats:sub>\n                    (X=Cl, I) afforded compounds\n                    <jats:bold>Ga\u2212Cl<\/jats:bold>\n                    and\n                    <jats:bold>Ga\u2212I<\/jats:bold>\n                    . The reaction between\n                    <jats:bold>Ga\u2212Cl<\/jats:bold>\n                    and Li[HBEt\n                    <jats:sub>3<\/jats:sub>\n                    ] in benzene yielded the dihydride compound\n                    <jats:bold>Ga\u2212H<\/jats:bold>\n                    . All reported compounds (\n                    <jats:bold>Ga\u2212Cl<\/jats:bold>\n                    ,\n                    <jats:bold>Ga\u2212I<\/jats:bold>\n                    , and\n                    <jats:bold>Ga\u2212H<\/jats:bold>\n                    ) were characterized by NMR, HRMS, and single\u2010crystal X\u2010ray diffraction studies.\n                    <jats:bold>Ga\u2212H<\/jats:bold>\n                    was probed for the hydroboration of carbodiimides (CDI), isocyanates, and isothiocyanates with HBpin. Compound\n                    <jats:bold>Ga\u2212H<\/jats:bold>\n                    was also found effective for the catalytic hydroboration of imines, nitriles, alkynes, esters, and formates, affording the corresponding products in quantitative yields. Stoichiometric reactions with a CDI were performed to establish the catalytic cycle.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202300737","type":"journal-article","created":{"date-parts":[[2024,3,4]],"date-time":"2024-03-04T12:29:51Z","timestamp":1709555391000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Gallium Hydride\u2010Catalyzed Selective Hydroboration of Unsaturated Organic Substrates"],"prefix":"10.1002","volume":"89","author":[{"given":"Sagrika","family":"Rajput","sequence":"first","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER), Homi Bhabha National Institute (HBNI)  Bhubaneswar 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajata Kumar","family":"Sahoo","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER), Homi Bhabha National Institute (HBNI)  Bhubaneswar 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nabin","family":"Sarkar","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER), Homi Bhabha National Institute (HBNI)  Bhubaneswar 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8856-4561","authenticated-orcid":false,"given":"Sharanappa","family":"Nembenna","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER), Homi Bhabha National Institute (HBNI)  Bhubaneswar 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,11]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","first-page":"313","volume":"2","author":"Ludwig J. 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