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Especially, when 20\u2005wt\u2009% KF was supported on the Mg\u2010Fe bi\u2010metal oxides and calcined at 400\u2013600\u2009\u00b0C, the solid material with more basic sites than the support itself was obtained. When applied as catalyst to dimethyl carbonate (DMC) synthesis through transesterification of ethylene carbonate (EC) and methanol, this material can afforded up to 88\u2009% yield and 97\u2009% selectivity toward DMC in 2\u2005h under reflux conditions with the molar ratio of methanol to ethylene carbonate set at 8. It is worth noting that the catalyst was easily separated and reused, retaining at least 89\u2009% catalytic activity during the first four recycles. Although an attenuated activity was still observed due to the inevitable filtration loss and dissolution, this solid base can still provide clues to the development recyclable catalyst in green synthesis of DMC.<\/jats:p>","DOI":"10.1002\/cplu.202300778","type":"journal-article","created":{"date-parts":[[2024,3,5]],"date-time":"2024-03-05T08:28:33Z","timestamp":1709627313000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis of Dimethyl Carbonate via Transesterification of Ethylene Carbonate and Methanol over Mesoporous KF\u2010loaded Mg\u2010Fe Oxides"],"prefix":"10.1002","volume":"89","author":[{"given":"Meng\u2010Ge","family":"Wei","sequence":"first","affiliation":[{"name":"College of Pharmacy Nankai University  38 Tongyan Road Tianjin 300350 P.\u2005R. 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