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Combination of organic electrochemistry with alternative approaches, such as photo\u2010chemistry was found to have great potential due to induced synergy effects. In this work, we propose for the first time utilization of plasmon triggering of enhanced and regio\u2010controlled organic chemical transformation performed in photoelectrochemical regime. The advantages of the proposed route is demonstrated in the model amination reaction with formation of C\u2212N bond between pyrazole and substituted benzene derivatives. Amination was performed in photo\u2010electrochemical mode on the surface of plasmon active Au@Pt electrode with attention focused on the impact of plasmon triggering on the reaction efficiency and regio\u2010selectivity. The ability to enhance the reaction rate significantly and to tune products regio\u2010selectivity is demonstrated. We also performed density functional theory calculations to inquire about the reaction mechanism and potentially explain the plasmon contribution to electrochemical reaction rate and regioselectivity.<\/jats:p>","DOI":"10.1002\/cplu.202400020","type":"journal-article","created":{"date-parts":[[2024,5,15]],"date-time":"2024-05-15T10:24:51Z","timestamp":1715768691000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Plasmon\u2010Mediated Organic Photoelectrochemistry Applied to Amination Reactions"],"prefix":"10.1002","volume":"89","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1082-0099","authenticated-orcid":false,"given":"Vladislav","family":"Buravets","sequence":"first","affiliation":[{"name":"Department of Solid State Engineering University of Chemistry and Technology  Technicka 5 166 28 Prague Czech 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