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They further were reacted with sodium azide in the presence of zinc(II) chloride to form 5\u2010((1\n                    <jats:italic>H<\/jats:italic>\n                    \u2010tetrazol\u20101\u2010yl)methyl)\u20101\n                    <jats:italic>H<\/jats:italic>\n                    \u2010tetrazole (1\u2010HTMT) and 5\u2010((2\n                    <jats:italic>H<\/jats:italic>\n                    \u2010tetrazol\u20102\u2010yl)methyl)\u20101\n                    <jats:italic>H<\/jats:italic>\n                    \u2010tetrazole (2\u2010HTMT). The nitrogen\u2010rich compounds have been applied as ligands for Energetic Coordination Compounds (ECCs) and show interesting coordinative behavior due to different bridging modes. The structural variability of the compounds has been proved by low\u2010temperature X\u2010ray analysis. The ECCs were analyzed for their sensitivities to provide information about the safety of handling and their capability to serve as primary explosives in detonator setups to replace the commonly used lead styphnate and azide. All colored ECCs were evaluated for their ignitability by laser initiation in translucent polycarbonate primer caps. In addition, the spin\u2010crossover characteristics of [Fe(1\u2010TAN)\n                    <jats:sub>6<\/jats:sub>\n                    ](ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    were highlighted by the measurement of the temperature\u2010dependent susceptibility curve.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202400031","type":"journal-article","created":{"date-parts":[[2024,3,4]],"date-time":"2024-03-04T06:34:34Z","timestamp":1709534074000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["1\u2010 and 2\u2010Tetrazolylacetonitrile as Versatile Ligands for Laser Ignitable Energetic Coordination Compounds"],"prefix":"10.1002","volume":"89","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1489-2380","authenticated-orcid":false,"given":"Simon M. 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