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Silver(I) ions were robustly immobilized on the amino\u2010functionalized chromium(III) terephthalate, which contains an imine bond formed by the reaction with PCy<jats:sub>2<\/jats:sub> aldehyde. The Ag(I) ion is coordinated with the phosphine in the imine group to create MIL\u2010101\u2010AP(Ag). Characterizations were carefully carried out according to the synthetic steps. The catalytic performance of MIL\u2010101\u2010AP(Ag) was evaluated through the C\u2212H carboxylation of thiophene\u20102\u2010carbonitrile, achieving a 10\u2009% yield with a turnover number of 1.0. The recyclability of the MIL\u2010101\u2010AP(Ag) catalyst was successfully demonstrated with five cycle, with no loss in activity and selectivity observed. This approach, which involves the formation of an imine bond to facilitate silver loading with phosphine on amino\u2010functionalized MIL\u2010101(Cr), exhibits significant potential for both CO<jats:sub>2<\/jats:sub> fixation and C\u2212H carboxylation, thereby highlighting the modified material\u2018s promise as a sustainable catalyst.<\/jats:p>","DOI":"10.1002\/cplu.202400096","type":"journal-article","created":{"date-parts":[[2024,3,25]],"date-time":"2024-03-25T00:43:25Z","timestamp":1711327405000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Immobilization of Silver(I) Ions on Amino\u2010Functionalized Chromium(III) Terephthalate with Organophosphine and its C\u2212H Carboxylation of a Heteroaromatic Compound"],"prefix":"10.1002","volume":"89","author":[{"given":"Mijung","family":"Lee","sequence":"first","affiliation":[{"name":"Green Carbon Research Center Korea Research Institute of Chemical Technology 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