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Particularly, three aluminosilicate mesostructured acid catalysts with catalytic activity towards methanol dehydration and featuring different porous structures (Al\u2010MCM\u201041, Al\u2010SBA\u201015, Al\u2010SBA\u201016) were synthesized and used as supports to host a CuO\/ZnO\/ZrO\n                    <jats:sub>2<\/jats:sub>\n                    (CZZ) CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation catalyst for methanol synthesis. The use of a mesostructured support allows to maximize the exposed surface of the CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction function by nanostructuring it through its confinement within the mesochannels, thus obtaining nanocomposite bifunctional catalysts with an ultra\u2010small hydrogenation nanophase. The nanocomposites were obtained using an impregnation strategy combined with a self\u2010combustion reaction, allowing to incorporate the CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction phase inside the mesopores. In all cases, the characterization shows that the hydrogenation phase species are highly and homogeneously dispersed into the supports as either small nanoparticles or as a nanolayer. The as\u2010obtained nanocomposites were tested for their catalytic activity and the results discussed taking into account the structural, textural, and acidic properties of the supports and nanocomposites.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202400760","type":"journal-article","created":{"date-parts":[[2025,1,23]],"date-time":"2025-01-23T11:24:17Z","timestamp":1737631457000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Confined Growth by Self\u2010Combustion of a Cu\u2010Based Nanophase into Mesostructured Acid Supports for DME Production from CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"90","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0842-9277","authenticated-orcid":false,"given":"Fausto","family":"Secci","sequence":"first","affiliation":[{"name":"Department of Chemical and Geological Sciences University of Cagliari  S.S.\u2005554 bivio per Sestu 09042 Monserrato CA Italy"},{"name":"Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM)  Via Giuseppe Giusti 9 50121 Firenze FI Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1899-8636","authenticated-orcid":false,"given":"Valentina","family":"Mameli","sequence":"additional","affiliation":[{"name":"Department of Chemical and Geological Sciences University of Cagliari  S.S.\u2005554 bivio per Sestu 09042 Monserrato CA Italy"},{"name":"Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM)  Via Giuseppe Giusti 9 50121 Firenze FI Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1593-5872","authenticated-orcid":false,"given":"Marco","family":"Sanna Angotzi","sequence":"additional","affiliation":[{"name":"Department of Chemical and Geological Sciences University of Cagliari  S.S.\u2005554 bivio per Sestu 09042 Monserrato CA Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1864-7964","authenticated-orcid":false,"given":"Luciano","family":"Atzori","sequence":"additional","affiliation":[{"name":"Department of Chemical and Geological Sciences University of Cagliari  S.S.\u2005554 bivio per Sestu 09042 Monserrato CA Italy"},{"name":"Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM)  Via Giuseppe Giusti 9 50121 Firenze FI Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lorenza","family":"Piroddi","sequence":"additional","affiliation":[{"name":"Sotacarbo S.p.A. 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